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用于光伏应用的基于MAPbX（X = Cl、Br、I）的钙钛矿的实验与理论研究

Experimental and Theoretical Investigations of MAPbX -Based Perovskites (X=Cl, Br, I) for Photovoltaic Applications.

作者信息

Mehra Sonali, Pandey Rahul, Madan Jaya, Sharma Rajnish, Goswami Lalit, Gupta Govind, Singh Vidya Nand, Srivastava Avanish Kumar, Sharma Shailesh Narain

机构信息

CSIR-, National Physical Laboratory, Dr K. S. Krishann Road, New Delhi, India, 110012.

AcSIR-, Academy of Scientific and Innovative Research, Ghaziabad, India, 201002.

出版信息

ChemistryOpen. 2024 Feb;13(2):e202300055. doi: 10.1002/open.202300055. Epub 2023 Oct 24.

DOI:10.1002/open.202300055
PMID:37874015
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10962479/
Abstract

This work mainly focuses on synthesizing and evaluating the efficiency of methylammonium lead halide-based perovskite (MAPbX ; X=Cl, Br, I) solar cells. We used the colloidal Hot-injection method (HIM) to synthesize MAPbX (X=Cl, Br, I) perovskites using the specific precursors and organic solvents under ambient conditions. We studied the structural, morphological and optical properties of MAPbX perovskites using XRD, FESEM, TEM, UV-Vis, PL and TRPL (time-resolved photoluminescence) characterization techniques. The particle size and morphology of these perovskites vary with respect to the halide variation. The MAPbI perovskite possesses a low band gap and low carrier lifetime but delivers the highest PCE among other halide perovskite samples, making it a promising candidate for solar cell technology. To further enrich the investigations, the conversion efficiency of the MAPbX perovskites has been evaluated through extensive device simulations. Here, the optical constants, band gap energy and carrier lifetime of MAPbX were used for simulating three different perovskite solar cells, namely I, Cl or Br halide-based perovskite solar cells. MAPbI , MAPbBr and MAPbCl absorber layer-based devices showed ~13.7 %, 6.9 % and 5.0 % conversion efficiency. The correlation between the experimental and SCAPS simulation data for HIM-synthesized MAPBX -based perovskites has been reported for the first time.

摘要

这项工作主要聚焦于合成和评估基于甲脒铅卤化物的钙钛矿（MAPbX ；X = Cl、Br、I）太阳能电池的效率。我们采用胶体热注入法（HIM），在环境条件下使用特定前驱体和有机溶剂合成MAPbX（X = Cl、Br、I）钙钛矿。我们使用XRD、FESEM、TEM、UV-Vis、PL和TRPL（时间分辨光致发光）表征技术研究了MAPbX钙钛矿的结构、形态和光学性质。这些钙钛矿的粒径和形态随卤化物的变化而变化。MAPbI钙钛矿具有低带隙和低载流子寿命，但在其他卤化物钙钛矿样品中具有最高的功率转换效率（PCE），使其成为太阳能电池技术的一个有前景的候选材料。为了进一步丰富研究内容，通过广泛的器件模拟评估了MAPbX钙钛矿的转换效率。在此，MAPbX的光学常数、带隙能量和载流子寿命被用于模拟三种不同的钙钛矿太阳能电池，即基于I、Cl或Br卤化物的钙钛矿太阳能电池。基于MAPbI 、MAPbBr和MAPbCl吸收层的器件显示出~13.7%、6.9%和5.0%的转换效率。首次报道了基于HIM合成的MAPBX钙钛矿的实验数据与SCAPS模拟数据之间的相关性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/265d/10962479/2a16f5109b1e/OPEN-13-e202300055-g006.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/265d/10962479/97cb480cd2cb/OPEN-13-e202300055-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/265d/10962479/b0d97fcc72ec/OPEN-13-e202300055-g010.jpg
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