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评估用于太阳能电池应用的铅基和无铅卤化物钙钛矿：一项模拟研究。

Evaluating Pb-based and Pb-free Halide Perovskites for Solar-Cell Applications: A Simulation Study.

作者信息

Mehra Sonali, Tawale Jai, Gupta Govind, Singh V N, Srivastava A K, Sharma Shailesh Narain

机构信息

CSIR - National Physical Laboratory, Dr. KS Krishnan Marg, New Delhi, 110012, India.

Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India.

出版信息

Heliyon. 2024 Jun 18;10(12):e33243. doi: 10.1016/j.heliyon.2024.e33243. eCollection 2024 Jun 30.

DOI:10.1016/j.heliyon.2024.e33243
PMID:39021962
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11253515/
Abstract

Metal halide Pb-based and Pb-free perovskite crystal structures are an essential class of optoelectronic materials due to their significant optoelectronic properties, optical absorption and tuneable emission spectrum properties. However, the most efficient optoelectronic devices were based on the Pb as a monovalent cation, but its toxicity is a significant hurdle for commercial device applications. Thus, replacing the toxic Pb with Pb-free alternatives (such as tin (Sn)) for diverse photovoltaic and optoelectronic applications is essential. Moreover, replacing the volatile methylammonium (MA) with cesium (Cs) leads to the development of an efficient perovskite absorber layer with improved optical & thermal stability and stabilized photoconversion efficiency. This paper discusses the correlation between the experimental and theoretical work for the Pb-based and Pb-free perovskites synthesised using the hot-injection method at different temperatures. Here, simulation is also carried out using the help of SCAPS-1D software to study the effect of various parameters of CsSnI and CsPbI layers on solar cell performance. This experimental and theoretical comparative study of the Hot-injection method synthesised CsPbI and CsSnI perovskites is rarely investigated for optoelectronic applications.

摘要

金属卤化物铅基和无铅钙钛矿晶体结构是一类重要的光电子材料，因其具有显著的光电性能、光吸收和可调发射光谱特性。然而，最有效的光电器件是以铅作为单价阳离子为基础的，但其毒性是商业器件应用的一个重大障碍。因此，用无铅替代品（如锡（Sn））替代有毒的铅用于各种光伏和光电子应用至关重要。此外，用铯（Cs）替代挥发性的甲铵（MA）可开发出具有 improved optical & thermal stability and stabilized photoconversion efficiency 的高效钙钛矿吸收层。本文讨论了在不同温度下使用热注入法合成的铅基和无铅钙钛矿的实验和理论工作之间的相关性。在此，还借助SCAPS-1D软件进行了模拟，以研究CsSnI和CsPbI层的各种参数对太阳能电池性能的影响。对于光电子应用，很少对热注入法合成的CsPbI和CsSnI钙钛矿进行这种实验和理论对比研究。 （注：原文中“improved optical & thermal stability and stabilized photoconversion efficiency”表述不太准确规范，推测可能是“改善的光学和热稳定性以及稳定的光转换效率” ）

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/1cd309429cb8/gr13.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/1cd309429cb8/gr13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/1fdbfc39dc38/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/19eae88b3c19/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/aa7cfca80e4b/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/586b213e9a9b/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/7200185e44f6/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/4a6342fb8cd6/gr6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/a734804fd856/gr7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/bcb6570abd71/gr8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/fedb246c1771/gr9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/3bab3704f4b6/gr10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/af4a63595a0b/gr11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/87e16fe33b52/gr12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/684f/11253515/1cd309429cb8/gr13.jpg

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