Cheng Pengfei, An Yidan, Jen Alex K-Y, Lei Dangyuan
Department of Materials Science and Engineering, City University of Hong Kong, Kowloon, Hong Kong, 999077, China.
The Hong Kong Institute for Clean Energy, City University of Hong Kong, Kowloon, Hong Kong, 999077, China.
Adv Mater. 2024 Apr;36(17):e2309459. doi: 10.1002/adma.202309459. Epub 2024 Jan 8.
Over the past decade, the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has experienced a remarkable ascent, soaring from 3.8% in 2009 to a remarkable record of 26.1% in 2023. Many recent approaches for improving PSC performance employ nanophotonic technologies, from light harvesting and thermal management to the manipulation of charge carrier dynamics. Plasmonic nanoparticles and arrayed dielectric nanostructures have been applied to tailor the light absorption, scattering, and conversion, as well as the heat dissipation within PSCs to improve their PCE and operational stability. In this review, it is begin with a concise introduction to define the realm of nanophotonics by focusing on the nanoscale interactions between light and surface plasmons or dielectric photonic structures. Prevailing strategies that utilize resonance-enhanced light-matter interactions for boosting the PCE and stability of PSCs from light trapping, carrier transportation, and thermal management perspectives are then elaborated, and the resultant practical applications, such as semitransparent photovoltaics, colored PSCs, and smart perovskite windows are discussed. Finally, the state-of-the-art nanophotonic paradigms in PSCs are reviewed, and the benefits of these approaches in improving the aesthetic effects and energy-saving character of PSC-integrated buildings are highlighted.
在过去十年中,钙钛矿太阳能电池(PSC)的功率转换效率(PCE)经历了显著提升,从2009年的3.8%飙升至2023年创纪录的26.1%。最近许多提高PSC性能的方法都采用了纳米光子技术,从光捕获和热管理到电荷载流子动力学的操控。等离子体纳米颗粒和阵列介电纳米结构已被用于调整PSC内的光吸收、散射和转换以及散热,以提高其PCE和运行稳定性。在本综述中,首先通过聚焦光与表面等离子体或介电光子结构之间的纳米级相互作用,对纳米光子学领域进行简要介绍。然后阐述了从光捕获、载流子传输和热管理角度利用共振增强光与物质相互作用来提高PSC的PCE和稳定性的主流策略,并讨论了由此产生的实际应用,如半透明光伏、彩色PSC和智能钙钛矿窗户。最后,对PSC中最先进的纳米光子范例进行了综述,并强调了这些方法在改善集成PSC的建筑美学效果和节能特性方面的益处。