K K Gopika, K Harsha Kumar, Ravichandran R, V Prasanth, S Kala, Jinesh K B, Mathew Oommen P, Ananthakumar S, Mohammed A Sri Peer
Department of Prosthodontics, Government Dental College, Thiruvananthapuram, Kerala, 695011, India.
Department of Physics, Indian Institute of Space Science and Technology, Thiruvananthapuram, Kerala, 695011, India.
Clin Oral Investig. 2023 Dec;27(12):7799-7807. doi: 10.1007/s00784-023-05369-5. Epub 2023 Nov 3.
The aim of this in vitro study was to evaluate the effect of an oxide nanocoating to prevent colour degradation of maxillofacial silicone elastomers following accelerated ageing.
Specimens (N = 40) of specified dimensions were fabricated in Factor II room temperature vulcanizing (RTV) silicone and processed according to the manufacturer's instructions. Two groups were classified with 20 specimens each. Specimens in the first group were coated with titanium dioxide (TiO) by atomic layer deposition technology. The colour stability test was conducted with a UV-VIS spectrometer (Schimadzu) for both titanium dioxide nanocoated and uncoated specimen groups after subjecting them to accelerated ageing. It was analysed using the CIE Lab method.
The average colour change was highest for uncoated specimens (2.868), and the average colour change for titanium dioxide-coated specimens was significantly low (1.774). The average colour change of uncoated specimens (2.868) was close to the acceptable threshold value (3), and that of coated specimens (1.774) was far below the acceptable threshold (3).
The colour change that occurred in titanium dioxide nanocoated specimens following accelerated ageing was significantly lower than that in the uncoated group, showing that the TiO nanocoating was effective in reducing the colour degradation of silicone elastomers.
Maxillofacial prostheses fabricated from silicone elastomers go through undesirable colour degradation over time. The development of a scientific technique that retards the colour deterioration of silicone prostheses would be of great clinical significance.
本体外研究的目的是评估一种氧化物纳米涂层在加速老化后防止颌面硅橡胶弹性体颜色降解的效果。
按照制造商的说明,在II型室温硫化(RTV)硅橡胶中制作特定尺寸的标本(N = 40)。将其分为两组,每组20个标本。第一组标本通过原子层沉积技术涂覆二氧化钛(TiO)。对二氧化钛纳米涂层和未涂层的标本组进行加速老化后,使用紫外可见光谱仪(岛津)进行颜色稳定性测试。采用CIE Lab方法进行分析。
未涂层标本的平均颜色变化最高(2.868),二氧化钛涂层标本的平均颜色变化显著较低(1.774)。未涂层标本的平均颜色变化(2.868)接近可接受阈值(3),而涂层标本的平均颜色变化(1.774)远低于可接受阈值(3)。
加速老化后,二氧化钛纳米涂层标本的颜色变化明显低于未涂层组,表明TiO纳米涂层可有效减少硅橡胶弹性体的颜色降解。
由硅橡胶弹性体制成的颌面假体随着时间的推移会出现不良的颜色降解。开发一种延缓硅橡胶假体颜色恶化的科学技术具有重要的临床意义。