Lai J H, Wang L L, Ko C C, DeLong R L, Hodges J S
LAI Laboratories, Inc., 12101 16th Avenue South, Burnsville, MN 55337, USA.
Dent Mater. 2002 May;18(3):281-6. doi: 10.1016/s0109-5641(01)00050-1.
The silicone elastomer A-2186 is a widely used maxillofacial prosthetic material. It is a pourable two-component silicone rubber cured by a platinum catalyst. Used as a prosthetic material, A-2186 has short working time and because of its hydrophobic nature, poor adhesion to non-silicone based adhesives. The purpose of this study is to evaluate the physical properties of new prosthetic materials based on methacryloxypropyl-terminated polydimethylsiloxane (MPDS-MF), and to compare the properties with those of A-2186.
Hardness, tensile strength, ultimate elongation, tear strength and adhesive bonding strength of MPDS-MF and A-2186 with and without additives were determined and compared. The bonding strengths of the extrinsic colorant carrier with the prosthetic materials were also determined. Statistical analyses were done using a two-way analysis of variance (ANOVA). For significant effects, post-hoc tests were done using the Bonferroni correction.
The hardness of MPDS-MF is similar to A-2186. However, tensile strength, tear strength, ultimate elongation, and adhesive bonding strength of MPDS-MF are higher than those of A-2186.
MPDS-MF is cured by free radical thermal polymerization and crosslinking. The working time of MPDS-MF, unlike A-2186, is long. The presence of methacrylate groups in MPDS-MF enhances its adhesion to non-silicone based adhesive. Based on the present study, it appears that MPDS-MF is suitable for use in fabricating of clinical prostheses.
硅酮弹性体A - 2186是一种广泛使用的颌面修复材料。它是一种可倾倒的双组分硅橡胶,由铂催化剂固化。作为修复材料,A - 2186的操作时间短,并且由于其疏水性,与非硅基粘合剂的粘附性差。本研究的目的是评估基于甲基丙烯酰氧基丙基封端的聚二甲基硅氧烷(MPDS - MF)的新型修复材料的物理性能,并将其性能与A - 2186的性能进行比较。
测定并比较了添加和未添加添加剂的MPDS - MF和A - 2186的硬度、拉伸强度、极限伸长率、撕裂强度和粘结强度。还测定了外部着色剂载体与修复材料的粘结强度。使用双向方差分析(ANOVA)进行统计分析。对于显著效应,使用Bonferroni校正进行事后检验。
MPDS - MF的硬度与A - 2186相似。然而,MPDS - MF的拉伸强度、撕裂强度、极限伸长率和粘结强度高于A - 2186。
MPDS - MF通过自由基热聚合和交联固化。与A - 2186不同,MPDS - MF的操作时间长。MPDS - MF中甲基丙烯酸酯基团的存在增强了其与非硅基粘合剂的粘附性。基于本研究,MPDS - MF似乎适用于临床假体的制造。