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生物炭作为直接甲醇燃料电池载体材料的催化性能:综述

Catalytic Properties of Biochar as Support Material Potential for Direct Methanol Fuel Cell: A Review.

作者信息

Visser Evan D, Seroka Ntalane S, Khotseng Lindiwe

机构信息

Department of Chemistry, University of the Western Cape, Robert Sobukwe Rd, Private Bag X17, Bellville 7535, South Africa.

出版信息

ACS Omega. 2023 Oct 26;8(44):40972-40981. doi: 10.1021/acsomega.3c02283. eCollection 2023 Nov 7.

Abstract

With the evolution and emergence of compounding environmental problems and issues, renewable energy promises to be a sustainable future technology. One technology considered is the fuel cell, which thrives on the primary function of electrocatalytic activities. Thus this review article envisages and presents a comprehensive summary of the applications of activated carbonaceous material as supports for electrocatalysts in fuel cells. The different techniques utilized to produce these carbon materials are discussed in detail. The overview architecture and the principle of the operation of fuel cells are also addressed. Additionally, electrocatalysts and the importance of support materials, their characteristics, and the role they play in the performance of the electrocatalyst will be reviewed. Unfortunately, the carbon-support-based electrocatalyst suffers long-term instability due to corrosion. Previously, carbon black has been used as a carbon support in various fuel cells. In recent years, there has been progress in the incorporation of nanostructured carbon supports in electrocatalysts in various fuel cells; however, there is still a great deal of distance to cover for nanostructured carbon-supported electrocatalysts in fuel cells to realize full commercialization and large-scale industrial purposes due to shortcomings in electrocatalysts, which are low-cost and highly efficient. This review therefore discusses the progress of incorporation of biochar extracted from sugar cane bagasse as carbon support in electrocatalysts for direct methanol fuel cells with the intention to provide insight into the quest of producing highly efficient and low cost fuel cells.

摘要

随着复合环境问题的演变和出现,可再生能源有望成为一种可持续的未来技术。其中一种被考虑的技术是燃料电池,它依赖于电催化活性的主要功能。因此,这篇综述文章设想并全面总结了活性炭质材料作为燃料电池电催化剂载体的应用。详细讨论了用于生产这些碳材料的不同技术。还阐述了燃料电池的总体架构和工作原理。此外,将对电催化剂以及载体材料的重要性、它们的特性以及在电催化剂性能中所起的作用进行综述。不幸的是,基于碳载体的电催化剂由于腐蚀而存在长期不稳定性。以前,炭黑已在各种燃料电池中用作碳载体。近年来,在各种燃料电池的电催化剂中纳入纳米结构碳载体方面取得了进展;然而,由于电催化剂存在低成本和高效方面的不足,纳米结构碳载电催化剂在燃料电池中实现全面商业化和大规模工业应用仍有很长的路要走。因此,本综述讨论了将从甘蔗渣中提取的生物炭作为直接甲醇燃料电池电催化剂的碳载体的纳入进展,旨在为生产高效低成本燃料电池的探索提供见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/159c/10634179/7062dad0f85d/ao3c02283_0004.jpg

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