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关于用作添加剂以提高生物柴油抗氧化降解稳定性的抗氧化剂的调查。

Survey on Antioxidants Used as Additives to Improve Biodiesel's Stability to Degradation through Oxidation.

作者信息

David Elena, Kopac Janez

机构信息

National Institute for Research and Development for Cryogenic and Isotopic Technologies, Street Uzinei No. 4, P.O. Râureni, P.O. Box 7, 240050 Ramnicu Valcea, Romania.

Faculty of Mechanical Engineering, University of Ljubljana, Askerceva 6, SI-1000 Ljubljana, Slovenia.

出版信息

Molecules. 2023 Nov 24;28(23):7765. doi: 10.3390/molecules28237765.

Abstract

A major problem that limits the use of biodiesel is maintaining the fuel at the specified standards for a longer period. Biodiesel oxidizes much more easily than diesel, and the final oxidation products change its physical and chemical properties and cause the formation of insoluble gums that can block fuel filters and the supply pipes. This instability of biodiesel is a major problem and has not yet been satisfactorily resolved. Recently, the use of biodiesel has increased quite a lot, but the problem related to oxidation could become a significant impediment. A promising and cost-effective approach to improving biodiesel's stability is to add appropriate antioxidants. Antioxidants work better or less effectively in different biodiesel fuels, and there is no one-size-fits-all inhibitor for every type of biodiesel fuel. To establish a suitable antioxidant for a certain type of biodiesel, it is necessary to know the chemistry of the antioxidants and factors that influence their effectiveness against biodiesel oxidation. Most studies on the use of antioxidants to improve the oxidative stability of biodiesel have been conducted independently. This study presents an analysis of these studies and mentions factors that must be taken into account for the choice of antioxidants so that the storage stability of biodiesel fuels can be improved.

摘要

限制生物柴油使用的一个主要问题是如何使燃料在较长时间内保持规定标准。生物柴油比柴油更容易氧化,最终的氧化产物会改变其物理和化学性质,并导致形成不溶性胶状物,从而堵塞燃油滤清器和供应管道。生物柴油的这种不稳定性是一个主要问题,尚未得到令人满意的解决。最近,生物柴油的使用量大幅增加,但与氧化相关的问题可能会成为一个重大障碍。一种有前景且经济高效的提高生物柴油稳定性的方法是添加合适的抗氧化剂。抗氧化剂在不同的生物柴油燃料中效果各异,不存在适用于每种生物柴油燃料的通用抑制剂。为某类生物柴油确定合适的抗氧化剂,有必要了解抗氧化剂的化学性质以及影响其对生物柴油氧化作用效果的因素。大多数关于使用抗氧化剂提高生物柴油氧化稳定性的研究都是独立进行的。本研究对这些研究进行了分析,并提及了选择抗氧化剂时必须考虑的因素,以便提高生物柴油燃料的储存稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d27f/10708488/7361a2a7f218/molecules-28-07765-g001.jpg

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