Maimon Ory, Li Qiliang
Department of Electrical Engineering, George Mason University, Fairfax, VA 22030, USA.
Nanoscale Device and Characterization Division, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA.
Materials (Basel). 2023 Dec 18;16(24):7693. doi: 10.3390/ma16247693.
Power electronics are becoming increasingly more important, as electrical energy constitutes 40% of the total primary energy usage in the USA and is expected to grow rapidly with the emergence of electric vehicles, renewable energy generation, and energy storage. New materials that are better suited for high-power applications are needed as the Si material limit is reached. Beta-phase gallium oxide (β-GaO) is a promising ultra-wide-bandgap (UWBG) semiconductor for high-power and RF electronics due to its bandgap of 4.9 eV, large theoretical breakdown electric field of 8 MV cm, and Baliga figure of merit of 3300, 3-10 times larger than that of SiC and GaN. Moreover, β-GaO is the only WBG material that can be grown from melt, making large, high-quality, dopable substrates at low costs feasible. Significant efforts in the high-quality epitaxial growth of β-GaO and β-(AlGa)O heterostructures has led to high-performance devices for high-power and RF applications. In this report, we provide a comprehensive summary of the progress in β-GaO field-effect transistors (FETs) including a variety of transistor designs, channel materials, ohmic contact formations and improvements, gate dielectrics, and fabrication processes. Additionally, novel structures proposed through simulations and not yet realized in β-GaO are presented. Main issues such as defect characterization methods and relevant material preparation, thermal studies and management, and the lack of p-type doping with investigated alternatives are also discussed. Finally, major strategies and outlooks for commercial use will be outlined.
电力电子学正变得越来越重要,因为电能在美国一次能源总使用量中占40%,并且随着电动汽车、可再生能源发电和储能的出现,预计还将迅速增长。由于达到了硅材料的极限,需要更适合高功率应用的新材料。β相氧化镓(β-GaO)是一种很有前景的超宽带隙(UWBG)半导体,适用于高功率和射频电子学,因为其带隙为4.9 eV,理论击穿电场高达8 MV/cm,以及巴利加优值为3300,比碳化硅和氮化镓大3至10倍。此外,β-GaO是唯一可以从熔体中生长的宽带隙材料,使得低成本制造大尺寸、高质量、可掺杂的衬底成为可能。在高质量外延生长β-GaO和β-(AlGa)O异质结构方面所做的大量努力,已经带来了适用于高功率和射频应用的高性能器件。在本报告中,我们全面总结了β-GaO场效应晶体管(FET)的进展,包括各种晶体管设计、沟道材料、欧姆接触形成与改进、栅极电介质和制造工艺。此外,还介绍了通过模拟提出但尚未在β-GaO中实现的新颖结构。还讨论了诸如缺陷表征方法及相关材料制备、热学研究与管理,以及缺乏p型掺杂及所研究的替代方案等主要问题。最后,将概述商业应用的主要策略和前景。