Musiienko Artem, Yang Fengjiu, Gries Thomas William, Frasca Chiara, Friedrich Dennis, Al-Ashouri Amran, Sağlamkaya Elifnaz, Lang Felix, Kojda Danny, Huang Yi-Teng, Stacchini Valerio, Hoye Robert L Z, Ahmadi Mahshid, Kanak Andrii, Abate Antonio
Solar Energy Division, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 12489, Berlin, Germany.
Chemistry and Nanoscience Center, National Renewable Energy Laboratory, Golden, CO, 80401, USA.
Nat Commun. 2024 Jan 5;15(1):316. doi: 10.1038/s41467-023-44418-1.
The knowledge of minority and majority charge carrier properties enables controlling the performance of solar cells, transistors, detectors, sensors, and LEDs. Here, we developed the constant light induced magneto transport method which resolves electron and hole mobility, lifetime, diffusion coefficient and length, and quasi-Fermi level splitting. We demonstrate the implication of the constant light induced magneto transport for silicon and metal halide perovskite films. We resolve the transport properties of electrons and holes predicting the material's effectiveness for solar cell application without making the full device. The accessibility of fourteen material parameters paves the way for in-depth exploration of causal mechanisms limiting the efficiency and functionality of material structures. To demonstrate broad applicability, we further characterized twelve materials with drift mobilities spanning from 10 to 10 cmVs and lifetimes varying between 10 and 10 seconds. The universality of our method its potential to advance optoelectronic devices in various technological fields.
对少数载流子和多数载流子特性的了解有助于控制太阳能电池、晶体管、探测器、传感器和发光二极管的性能。在此,我们开发了恒光诱导磁输运方法,该方法可解析电子和空穴的迁移率、寿命、扩散系数和长度以及准费米能级分裂。我们展示了恒光诱导磁输运对硅和金属卤化物钙钛矿薄膜的影响。我们解析了电子和空穴的输运特性,在不制造完整器件的情况下预测材料在太阳能电池应用中的有效性。十四个材料参数的可获取性为深入探索限制材料结构效率和功能的因果机制铺平了道路。为了证明其广泛适用性,我们进一步对十二种材料进行了表征,其漂移迁移率范围为10至10 cmVs,寿命在10至10秒之间变化。我们方法的通用性及其在各种技术领域推进光电器件的潜力。