Research Center for New Energy Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai, China.
University of Chinese Academy of Sciences, Beijing, China.
Nature. 2023 May;617(7962):717-723. doi: 10.1038/s41586-023-05921-z. Epub 2023 May 24.
Flexible solar cells have a lot of market potential for application in photovoltaics integrated into buildings and wearable electronics because they are lightweight, shockproof and self-powered. Silicon solar cells have been successfully used in large power plants. However, despite the efforts made for more than 50 years, there has been no notable progress in the development of flexible silicon solar cells because of their rigidity. Here we provide a strategy for fabricating large-scale, foldable silicon wafers and manufacturing flexible solar cells. A textured crystalline silicon wafer always starts to crack at the sharp channels between surface pyramids in the marginal region of the wafer. This fact enabled us to improve the flexibility of silicon wafers by blunting the pyramidal structure in the marginal regions. This edge-blunting technique enables commercial production of large-scale (>240 cm), high-efficiency (>24%) silicon solar cells that can be rolled similarly to a sheet of paper. The cells retain 100% of their power conversion efficiency after 1,000 side-to-side bending cycles. After being assembled into large (>10,000 cm) flexible modules, these cells retain 99.62% of their power after thermal cycling between -70 °C and 85 °C for 120 h. Furthermore, they retain 96.03% of their power after 20 min of exposure to air flow when attached to a soft gasbag, which models wind blowing during a violent storm.
柔性太阳能电池在光伏建筑一体化和可穿戴电子领域有很大的市场潜力,因为它们重量轻、耐冲击、自供电。硅太阳能电池已成功应用于大型发电厂。然而,尽管 50 多年来一直在努力,但是由于其刚性,柔性硅太阳能电池的发展并没有取得显著的进展。在这里,我们提供了一种制造大规模可折叠硅片和制造柔性太阳能电池的策略。纹理化的晶体硅片总是从晶圆边缘区域表面金字塔之间的尖锐通道开始开裂。这一事实使我们能够通过钝化晶圆边缘区域的金字塔结构来提高硅片的柔韧性。这种边缘钝化技术使商业生产大规模(>240cm)、高效率(>24%)的硅太阳能电池成为可能,这些电池可以像纸一样卷起来。这些电池在经过 1000 次左右弯曲循环后仍保持 100%的功率转换效率。在组装成大型(>10000cm)柔性模块后,这些电池在-70°C 至 85°C 之间进行 120 小时的热循环后仍保留 99.62%的功率。此外,当它们附着在软气囊上并暴露在气流中 20 分钟后,仍保留 96.03%的功率,这模拟了暴风中的强风。