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具有3.7%单轴拉伸应变的超高质量玻璃上锗。

Ultrahigh-Quality Ge-on-Glass with a 3.7% Uniaxial Tensile Strain.

作者信息

Wang Liming, Xia Guangrui

机构信息

Department of Materials Engineering, The University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada.

出版信息

ACS Omega. 2024 Feb 14;9(8):9753-9764. doi: 10.1021/acsomega.3c09980. eCollection 2024 Feb 27.

DOI:10.1021/acsomega.3c09980
PMID:38434815
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10906031/
Abstract

While there have been notable advancements in the quality of epitaxial Ge on Si, the crystal quality of bulk Ge remains much superior, which provides an effective method to study the performance potentials of Ge-based semiconductor devices. This study showcases the development of ultrahigh-quality Ge/poly-Si/SiO on glass with a Ge thickness reduced to ≤100 nm (10 μm width) through wafer bonding, thinning, and polishing processes. The minority lifetimes measured for the Ge thin films range between 200 and 1000 ns, surpassing those achieved with epi-Ge on Si by at least 20 to 100 times. The wafer bonding process introduces a desirable tensile strain of 0.1%, attributed to thermal expansion mismatch. A Ge microbridge structure was employed to amplify the tensile strain, reaching a maximum uniaxial tensile strain of 3.7%. The much longer minority carrier lifetime together with the strain-induced band gap engineering holds promise for improving light emission efficiency. This work establishes an economical and convenient method for producing high-quality tensile-strained Ge thin films, a pivotal step in exploring the potential of Ge in light emission applications.

摘要

虽然硅基外延锗的质量已有显著进步,但块状锗的晶体质量仍要优越得多,这为研究锗基半导体器件的性能潜力提供了一种有效方法。本研究展示了通过晶圆键合、减薄和抛光工艺,在玻璃上制备出锗厚度减小至≤100纳米(宽度为10微米)的超高质量锗/多晶硅/二氧化硅结构。锗薄膜的少数载流子寿命在200到1000纳秒之间,比硅基外延锗至少高出20到100倍。晶圆键合工艺因热膨胀失配引入了0.1%的理想拉伸应变。采用锗微桥结构放大拉伸应变,达到了3.7%的最大单轴拉伸应变。长得多的少数载流子寿命以及应变诱导的带隙工程有望提高发光效率。这项工作建立了一种经济便捷的方法来生产高质量的拉伸应变锗薄膜,这是探索锗在发光应用中潜力的关键一步。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/ab3aa079e33b/ao3c09980_0014.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/a84ff74f0546/ao3c09980_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/81a3031cf2b7/ao3c09980_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/b14d5c1c9a98/ao3c09980_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/d308d357e718/ao3c09980_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/d539c8099d8e/ao3c09980_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/c1fed380b0da/ao3c09980_0007.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/1e7ba047c78a/ao3c09980_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/1b1c5b2d07d9/ao3c09980_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/f21c96a31580/ao3c09980_0011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3277/10906031/ab3aa079e33b/ao3c09980_0014.jpg

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本文引用的文献

1
Sub-10 μm-Thick Ge Thin Film Fabrication from Bulk-Ge Substrates via a Wet Etching Method.通过湿法蚀刻法从块状锗衬底制备厚度小于10μm的锗薄膜。
ACS Omega. 2023 Dec 12;8(51):49201-49210. doi: 10.1021/acsomega.3c07490. eCollection 2023 Dec 26.
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On-chip optical interconnection using integrated germanium light emitters and photodetectors.使用集成锗发光器和光电探测器的片上光互连。
Opt Express. 2021 Aug 30;29(18):28021-28036. doi: 10.1364/OE.432324.
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An electrically pumped germanium laser.一种电泵浦锗激光器。
Opt Express. 2012 May 7;20(10):11316-20. doi: 10.1364/OE.20.011316.
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Hybrid plasma bonding for void-free strong bonded interface of silicon/glass at 200 degrees C.200℃下实现硅/玻璃无空洞强键合界面的混合等离子体键合。
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Ge-on-Si laser operating at room temperature.室温下工作的 Ge-on-Si 激光。
Opt Lett. 2010 Mar 1;35(5):679-81. doi: 10.1364/OL.35.000679.
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Tensile-strained, n-type Ge as a gain medium for monolithic laser integration on Si.拉伸应变的n型锗作为用于在硅上进行单片激光集成的增益介质。
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