Liu Wenchao, Mei Tingting, Cao Zhouwen, Li Chun, Wu Yitian, Wang Li, Xu Guoheng, Chen Yuanxia, Zhou You, Wang Senyao, Xue Yahui, Yu Yanhao, Kong Xiang-Yu, Chen Ruotian, Tu Bin, Xiao Kai
Guangdong Provincial Key Laboratory of Advanced Biomaterials, Department of Biomedical Engineering, Southern University of Science and Technology, Shenzhen 518055, P.R. China.
Laboratory of Theoretical and Computational Nanoscience, CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P.R. China.
Sci Adv. 2024 Mar 15;10(11):eadj7867. doi: 10.1126/sciadv.adj7867. Epub 2024 Mar 13.
The voltage-gated ion channels, also known as ionic transistors, play substantial roles in biological systems and ion-ion selective separation. However, implementing the ultrafast switchable capabilities and polarity switching of ionic transistors remains a challenge. Here, we report a nanofluidic ionic transistor based on carbon nanotubes, which exhibits an on/off ratio of 10 at operational gate voltage as low as 1 V. By controlling the morphology of carbon nanotubes, both unipolar and ambipolar ionic transistors are realized, and their on/off ratio can be further improved by introducing an AlO dielectric layer. Meanwhile, this ionic transistor enables the polarity switching between p-type and n-type by controlled surface properties of carbon nanotubes. The implementation of constructing ionic circuits based on ionic transistors is demonstrated, which enables the creation of NOT, NAND, and NOR logic gates. The ionic transistors are expected to have profound implications for low-energy consumption computing devices and brain-machine interfacing.
电压门控离子通道,也被称为离子晶体管,在生物系统和离子-离子选择性分离中发挥着重要作用。然而,实现离子晶体管的超快可切换能力和极性切换仍然是一个挑战。在此,我们报道了一种基于碳纳米管的纳米流体离子晶体管,其在低至1V的工作栅极电压下表现出10的开/关比。通过控制碳纳米管的形态,实现了单极和双极离子晶体管,并且通过引入AlO介电层可以进一步提高它们的开/关比。同时,这种离子晶体管通过控制碳纳米管的表面性质实现了p型和n型之间的极性切换。展示了基于离子晶体管构建离子电路的实现,这使得能够创建非、与非和或非逻辑门。离子晶体管有望对低能耗计算设备和脑机接口产生深远影响。