Elendu Collins Chimezie, Liu Chang, Aleem Rao Danish, Shan Yaqi, Cao Changqing, Ramzan Naveed, Duan Pei-Gao
Shaanxi Key Laboratory of Energy Chemical Process Intensification, School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China.
P-129 Staff Colony, University of Engineering and Technology, Lahore GT Road, Lahore 39161, Pakistan.
ACS Omega. 2024 Mar 6;9(11):12941-12955. doi: 10.1021/acsomega.3c09186. eCollection 2024 Mar 19.
The integration of optimization techniques and deep learning models, which offer a promising avenue for improving the efficiency and sustainability of biodiesel production processes from baobab seed oil (BSO), is rare. This study utilized a multi-input-multioutput (MIMO) deep learning technique and the most recent central composite design (CCD) optimization tool to model and optimize the yield and properties of biodiesel produced from BSO. First, the baobab seed oil was extracted using a solvent extraction method. BSO was subsequently analyzed and converted to biodiesel by reacting CHOH catalyzed by waste banana bunch stalk biochar activated by KOH. Multiobjective optimization and prediction of the biodiesel yield () and several key fuel properties, including the cetane number (CN), kinematic viscosity (VS), and purity (), were achieved. With better correlation coefficients of 0.9709, 0.9464, and 0.9714 for response training, response testing, and response validation, respectively, and a root-mean-square error of 0.00755, the MIMO model on the logsig transfer function accurately predicted the biodiesel yield and properties more than did the MISO and response surface methodology models. The optimum (96 wt %), CN (48), VS (3.3 mm/s), and (98.3%) were concurrently accomplished at a reaction temperature of 56 °C, a reaction time of 115 min, a CHOH/BSO molar ratio of 15:1, a catalyst dosage of 6 wt %, and a stirring speed of 400 rpm with 98% optimal validation accuracy. CCD sensitivity analysis revealed that the CHOH/BSO ratio was the most sensitive (50.9%) input predictor among the other input variables studied.
优化技术与深度学习模型的整合为提高从猴面包树籽油(BSO)生产生物柴油过程的效率和可持续性提供了一条很有前景的途径,但这种整合很少见。本研究利用多输入多输出(MIMO)深度学习技术和最新的中心复合设计(CCD)优化工具,对由BSO生产的生物柴油的产率和性能进行建模和优化。首先,采用溶剂萃取法提取猴面包树籽油。随后对BSO进行分析,并通过在由KOH活化的废弃香蕉束茎生物炭催化下与CHOH反应将其转化为生物柴油。实现了生物柴油产率()以及包括十六烷值(CN)、运动粘度(VS)和纯度()在内的几个关键燃料性能的多目标优化和预测。对于响应训练、响应测试和响应验证,相关系数分别为0.9709、0.9464和0.9714,均方根误差为0.00755,基于对数Sigmoid传递函数的MIMO模型比单输入单输出(MISO)和响应面方法模型更准确地预测了生物柴油的产率和性能。在反应温度为56℃、反应时间为115分钟、CHOH/BSO摩尔比为15:1、催化剂用量为6wt%、搅拌速度为400rpm的条件下,同时实现了最佳产率(96wt%)、CN(48)、VS(3.3mm/s)和纯度(98.3%),最佳验证准确率为98%。CCD灵敏度分析表明,在所研究的其他输入变量中,CHOH/BSO比例是最敏感的输入预测因子(50.9%)。