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双金属有机框架在棉织物上的生长:可回收光催化纺织品的超声合成策略

growth of Bi-MOF on cotton fabrics ultrasonic synthesis strategy for recyclable photocatalytic textiles.

作者信息

Qin Hengjie, Lv Ying, Nakane Koji

机构信息

Frontier Fiber Technology and Science, University of Fukui Bunkyo 3-9-1 Fukui 910-8507 Japan

New Energy College, Xi'an Shiyou University No. 18 East Section 2nd Dianzi Road Xi'an 710065 China.

出版信息

RSC Adv. 2024 Apr 9;14(16):11513-11523. doi: 10.1039/d4ra00493k. eCollection 2024 Apr 3.

Abstract

Bismuth-based metal-organic framework (Bi-MOF) materials have shown potential for treating organic pollutants. In this work, multifunctional textiles were produced by synthesis of CAU-17 on carboxymethylated cotton fabrics by solvothermal and ultrasonic strategies and employed as recyclable photocatalysts. The compositional and structural features of the dense MOF crystal coatings on cotton fibers were confirmed by scanning electron microscopy, X-ray diffraction, and other characterization approaches. Under optimized conditions, the developed functionalized cotton fabrics achieved a photodegradation efficiency of 98.8% under visible light for RhB in water, as well as good recyclability. The described results have provided the basis and reference for the fabrication of MOF-functionalized textiles.

摘要

铋基金属有机框架(Bi-MOF)材料已显示出处理有机污染物的潜力。在这项工作中,通过溶剂热和超声策略在羧甲基化棉织物上合成CAU-17制备了多功能纺织品,并将其用作可回收光催化剂。通过扫描电子显微镜、X射线衍射和其他表征方法证实了棉纤维上致密MOF晶体涂层的组成和结构特征。在优化条件下,所制备的功能化棉织物在可见光下对水中罗丹明B的光降解效率达到98.8%,并且具有良好的可回收性。上述结果为MOF功能化纺织品的制备提供了依据和参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb04/11002839/50a617cf7860/d4ra00493k-f1.jpg

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