Tănase Maria Antonia, Soare Andreia Cristina, Oancea Petruţa, Răducan Adina, Mihăescu Cătălin Ionuţ, Alexandrescu Elvira, Petcu Cristian, Diţu Lia Mara, Ferbinteanu Marilena, Cojocaru Bogdan, Cinteza Ludmila Otilia
Physical Chemistry Department, Faculty of Chemistry, University of Bucharest, 4-12 Regina Elisabeta Blv., 030018 Bucharest, Romania.
Polymers Department, National Institute for Research and Development in Chemistry and Petrochemistry-ICECHIM, 202 Spl. Independentei, 060021 Bucharest, Romania.
Nanomaterials (Basel). 2021 Sep 30;11(10):2574. doi: 10.3390/nano11102574.
ZnO nanoparticle-based multifunctional coatings were prepared by a simple, time-saving microwave method. Arginine and ammonia were used as precipitation agents, and zinc acetate dehydrate was used as a zinc precursor. Under the optimized conditions, flower-like morphologies of ZnO aggregates were obtained. The prepared nanopowders were characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and UV/Visible spectroscopy. The developed in situ synthesis with microwave irradiation enabled significant ZnO nanoparticle deposition on cotton fabrics, without additional steps. The functionalized textiles were tested as a photocatalyst in methylene blue (MB) photodegradation and showed good self-cleaning and UV-blocking properties. The coated cotton fabrics exhibited good antibacterial properties against common microbial trains (, and ), together with self-cleaning and photocatalytic efficiency in organic dye degradation. The proposed microwave-assisted in situ synthesis of ZnO nanocoatings on textiles shows high potential as a rapid, efficient, environmentally friendly, and scalable method to fabricate functional fabrics.
采用简单、省时的微波法制备了基于氧化锌纳米颗粒的多功能涂层。以精氨酸和氨水为沉淀剂,以醋酸锌二水合物为锌前驱体。在优化条件下,获得了氧化锌聚集体的花状形貌。使用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)和紫外/可见光谱对制备的纳米粉末进行了表征。通过微波辐射进行的原位合成能够在棉织物上大量沉积氧化锌纳米颗粒,无需额外步骤。对功能化纺织品作为光催化剂用于亚甲基蓝(MB)光降解进行了测试,结果表明其具有良好的自清洁和紫外线阻挡性能。涂覆的棉织物对常见微生物菌株(、和)表现出良好的抗菌性能,同时在有机染料降解方面具有自清洁和光催化效率。所提出的微波辅助原位合成纺织品上氧化锌纳米涂层的方法,作为一种快速、高效、环境友好且可扩展的制备功能织物的方法,具有很高的潜力。