• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

镝到镱的能量转移及其在发光测温中的应用洞察

Insights into Nd to Yb Energy Transfer and Its Implications in Luminescence Thermometry.

作者信息

Oggianu Mariangela, Mameli Valentina, Hernández-Rodríguez Miguel A, Monni Noemi, Souto Manuel, Brites Carlos D S, Cannas Carla, Manna Fabio, Quochi Francesco, Cadoni Enzo, Masciocchi Norberto, Carneiro Neto Albano N, Carlos Luís D, Mercuri Maria Laura

机构信息

Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, Monserrato I-09042, Italy.

INSTM, Via Giuseppe Giusti, 9, Firenze 50121, Italy.

出版信息

Chem Mater. 2024 Mar 28;36(7):3452-3463. doi: 10.1021/acs.chemmater.4c00362. eCollection 2024 Apr 9.

DOI:10.1021/acs.chemmater.4c00362
PMID:38617804
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11008107/
Abstract

This work challenges the conventional approach of using NdF lifetime changes for evaluating the experimental Nd → Yb energy transfer rate and efficiency. Using near-infrared (NIR) emitting Nd:Yb mixed-metal coordination polymers (CPs), synthesized via solvent-free thermal grinding, we demonstrate that the Nd [H → I] → Yb [F → F] pathway, previously overlooked, dominates energy transfer due to superior energy resonance and -level selection rule compatibility. This finding upends the conventional focus on the Nd [F → I] → Yb [F → F] transition pathway. We characterized NdYb(BTC)(HO) as a promising cryogenic NIR thermometry system and employed our novel energy transfer understanding to perform simulations, yielding theoretical thermometric parameters and sensitivities for diverse Nd:Yb ratios. Strikingly, experimental thermometric data closely matched the theoretical predictions, validating our revised model. This novel perspective on Nd → Yb energy transfer holds general applicability for the Nd/Yb pair, unveiling an important spectroscopic feature with broad implications for energy transfer-driven materials design.

摘要

这项工作挑战了使用钕（Nd）荧光寿命变化来评估实验性钕到镱（Nd→Yb）能量转移速率和效率的传统方法。通过无溶剂热研磨合成近红外（NIR）发射的钕：镱混合金属配位聚合物（CPs），我们证明了之前被忽视的Nd [H→I]→Yb [F→F]途径，由于卓越的能量共振和能级选择规则兼容性，在能量转移中占主导地位。这一发现颠覆了传统上对Nd [F→I]→Yb [F→F]跃迁途径的关注。我们将NdYb(BTC)(HO)表征为一种有前景的低温NIR测温系统，并利用我们对能量转移的新理解进行模拟，得出了不同钕：镱比例下的理论测温参数和灵敏度。令人惊讶的是，实验测温数据与理论预测紧密匹配，验证了我们修正后的模型。这种关于Nd→Yb能量转移的新观点对Nd/Yb对具有普遍适用性，揭示了一个重要的光谱特征，对能量转移驱动的材料设计具有广泛影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/058cbce54aab/cm4c00362_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/8009706bb822/cm4c00362_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/f19f533c8abf/cm4c00362_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/9139547ef74c/cm4c00362_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/c2daace578e0/cm4c00362_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/660a0dfc0ff3/cm4c00362_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/058cbce54aab/cm4c00362_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/8009706bb822/cm4c00362_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/f19f533c8abf/cm4c00362_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/9139547ef74c/cm4c00362_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/c2daace578e0/cm4c00362_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/660a0dfc0ff3/cm4c00362_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b312/11008107/058cbce54aab/cm4c00362_0005.jpg

相似文献

1
Insights into Nd to Yb Energy Transfer and Its Implications in Luminescence Thermometry.镝到镱的能量转移及其在发光测温中的应用洞察
Chem Mater. 2024 Mar 28;36(7):3452-3463. doi: 10.1021/acs.chemmater.4c00362. eCollection 2024 Apr 9.
2
Enhancement of the NIR Emission of Cr-Yb Co-doped LaGaGeO Phosphors by Doping Nd Ions via Efficient Energy Transfer for NIR Spectroscopy Regulation.通过高效能量传递掺杂 Nd 离子增强 Cr-Yb 共掺 LaGaGeO 荧光粉的近红外发射用于近红外光谱调控。
Inorg Chem. 2022 Aug 29;61(34):13618-13626. doi: 10.1021/acs.inorgchem.2c02530. Epub 2022 Aug 16.
3
NIR luminescence lifetime nanothermometry based on phonon assisted Yb-Nd energy transfer.基于声子辅助镱-钕能量转移的近红外发光寿命纳米测温法。
Nanoscale Adv. 2021 Jun 14;3(17):4918-4925. doi: 10.1039/d1na00285f. eCollection 2021 Aug 25.
4
Alkali Silicates Codoped with NIR-Emitting RE (Nd and Yb) Ions for Thermometry Applications.用于测温应用的掺有近红外发射稀土（钕和镱）离子的碱金属硅酸盐
J Fluoresc. 2025 Jun;35(6):4099-4110. doi: 10.1007/s10895-024-03794-7. Epub 2024 Jul 2.
5
DNA Intercalating Near-Infrared Luminescent Lanthanide Complexes Containing Dipyrido[3,2-:2',3'-]phenazine (dppz) Ligands: Synthesis, Crystal Structures, Stability, Luminescence Properties and CT-DNA Interaction.含二吡啶并[3,2-:2',3'-]吩嗪（dppz）配体的 DNA 插入型近红外发光镧系配合物的合成、晶体结构、稳定性、发光性能及与 CT-DNA 的相互作用。
Molecules. 2020 Nov 13;25(22):5309. doi: 10.3390/molecules25225309.
6
Comprehensive investigations of near infrared downshift and upconversion luminescence mechanisms in Yb single-doped and Er,Yb co-doped SiO inverse opals.Yb单掺杂和Er、Yb共掺杂SiO反蛋白石中近红外下转换和上转换发光机制的综合研究。
Phys Chem Chem Phys. 2017 Dec 6;19(47):31997-32006. doi: 10.1039/c7cp06622h.
7
Structural and photophysical properties of coordination networks combining [Ru(Bpym)(CN)4]2- or [[Ru(CN)4]2(mu-bpym)]4- anions (bpym = 2,2'-bipyrimidine) with lanthanide(III) cations: sensitized near-infrared luminescence from Yb(III), Nd(III), and Er(III) following Ru-to-lanthanide energy transfer.将[Ru(Bpym)(CN)₄]²⁻或[[Ru(CN)₄]₂(μ-bpym)]⁴⁻阴离子（bpym = 2,2'-联嘧啶）与镧系(III)阳离子相结合的配位网络的结构和光物理性质：钌到镧系元素的能量转移后Yb(III)、Nd(III)和Er(III)的近红外敏化发光。
Inorg Chem. 2006 May 15;45(10):3895-904. doi: 10.1021/ic0521574.
8
Near infrared absorbing near infrared emitting highly-sensitive luminescent nanothermometer based on Nd(3+) to Yb(3+) energy transfer.基于Nd(3+)到Yb(3+)能量转移的近红外吸收和近红外发射高灵敏度发光纳米温度计
Phys Chem Chem Phys. 2015 Oct 7;17(37):24315-21. doi: 10.1039/c5cp03861h. Epub 2015 Sep 1.
9
All near-infrared multiparametric luminescence thermometry using Er, Yb-doped YAG nanoparticles.所有使用掺铒、镱的钇铝石榴石纳米颗粒的近红外多参数发光测温法。
RSC Adv. 2021 Apr 29;11(26):15933-15942. doi: 10.1039/d1ra01647d. eCollection 2021 Apr 26.
10
[Ru(bipy)(3)](2+) and [Os(bipy)(3)](2+) chromophores as sensitisers for near-infrared luminescence from Yb(iii) and Nd(iii) in d/f dyads: contributions from Förster, Dexter, and redox-based energy-transfer mechanisms.[钌（联吡啶）₃]²⁺和[锇（联吡啶）₃]²⁺发色团作为d/f二元体系中镱（Ⅲ）和钕（Ⅲ）近红外发光的敏化剂：福斯特、德克斯特和基于氧化还原的能量转移机制的贡献
Dalton Trans. 2009 May 28(20):3971-9. doi: 10.1039/b901560d. Epub 2009 Mar 10.

引用本文的文献

1
Anti-thermal quenching in Nd molecular near-infrared thermometers operating at physiological temperatures.在生理温度下工作的钕分子近红外温度计中的抗热猝灭。
Commun Chem. 2025 May 3;8(1):136. doi: 10.1038/s42004-025-01536-9.
2
Luminescent Thermometer Based on a Praseodymium(iii) Cyanide-Based Metal-Organic Framework.基于氰化镨（III）基金属有机框架的发光温度计。
Inorg Chem. 2025 Jan 13;64(1):192-201. doi: 10.1021/acs.inorgchem.4c04436. Epub 2024 Dec 19.
3
Thiophenyl Anilato-Based NIR-Emitting Lanthanide (Ln = Er, Yb) Dinuclear Complexes.

本文引用的文献

1
Engineering of metal-organic frameworks (MOFs) for thermometry.用于测温的金属有机骨架（MOFs）的工程设计。
Dalton Trans. 2023 Jun 6;52(22):7383-7404. doi: 10.1039/d3dt01048a.
2
Seeking Brightness in Molecular Erbium-Based Light Upconversion.探寻基于铒的分子上转换发光中的光明前景。
J Am Chem Soc. 2023 Apr 5. doi: 10.1021/jacs.3c01331.
3
Local Temperature Increments and Induced Cell Death in Intracellular Magnetic Hyperthermia.细胞内磁共振热疗中的局部温度升高和诱导细胞死亡。
基于硫代苯基苯胺基的近红外发光镧系元素（Ln = Er，Yb）双核配合物。
Molecules. 2024 Dec 9;29(23):5804. doi: 10.3390/molecules29235804.
4
Energy exchange between Nd and Er centers within molecular complexes.分子络合物中钕（Nd）和铒（Er）中心之间的能量交换。
Chem Sci. 2024 Oct 18;15(44):18295-302. doi: 10.1039/d4sc03994g.
ACS Nano. 2023 Apr 11;17(7):6822-6832. doi: 10.1021/acsnano.3c00388. Epub 2023 Mar 20.
4
Tunable Optical Molecular Thermometers Based on Metallacrowns.基于金属冠醚的可调谐光学生物质温度计。
J Am Chem Soc. 2022 Oct 12;144(40):18259-18271. doi: 10.1021/jacs.2c04821. Epub 2022 Sep 29.
5
Modulation of Local Cellular Activities using a Photothermal Dye-Based Subcellular-Sized Heat Spot.基于光热染料的亚细胞级热斑调控局部细胞活性
ACS Nano. 2022 Jun 28;16(6):9004-9018. doi: 10.1021/acsnano.2c00285. Epub 2022 Jun 8.
6
Challenges for optical nanothermometry in biological environments.生物环境中光热测量的挑战。
Chem Soc Rev. 2022 Jun 6;51(11):4223-4242. doi: 10.1039/d2cs00069e.
7
NIR luminescence thermometers based on Yb-Nd coordination compounds for the 83-393 K temperature range.基于 Yb-Nd 配位化合物的近红外发光温度计，用于 83-393 K 的温度范围。
Dalton Trans. 2022 Apr 5;51(14):5419-5425. doi: 10.1039/d2dt00147k.
8
Near-Infrared-to-Near-Infrared Optical Thermometer BaYO: Yb/Nd Assembled with Photothermal Conversion Performance.近红外至近红外光热温度计 BaYO:Yb/Nd 与光热转换性能组装。
Inorg Chem. 2022 Apr 4;61(13):5425-5432. doi: 10.1021/acs.inorgchem.2c00432. Epub 2022 Mar 25.
9
Spectroscopic aspects for the Yb coordination compound with a large energy gap between the ligand and Yb excited states.镱配位化合物的光谱学方面，该化合物在配体与镱激发态之间存在较大的能隙。
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Jun 5;274:121072. doi: 10.1016/j.saa.2022.121072. Epub 2022 Feb 24.
10
Lanthanide doped luminescence nanothermometers in the biological windows: strategies and applications.生物窗口中的镧系掺杂发光纳米温度计：策略与应用
Nanoscale. 2021 May 7;13(17):7913-7987. doi: 10.1039/d0nr09150b. Epub 2021 Apr 26.