Highly Efficient Conversion of Salinity Difference to Electricity in Nanofluidic Channels Boosted by Variable Thickness Polyelectrolyte Coating.

The inherent limits of the current produced by imposing salinity gradients along a nanofluidic channel having "hard" boundary walls heavily constrain the resulting energy harvesting efficacy, acting as major hindrances against the practicability of harnessing high power density from the mixing of water having different salinities. In this work, the infusion of variable-thickness polyelectrolyte layer of a conical shape is projected to augment salinity gradient power generation in nanochannels. Such a progressive thickening of a charged interfacial layer on account of axially declining ion concentration facilitates the shedding of enhanced numbers of mobile ions, bearing a net charge of equal and opposite to the surface-bound ions, into the mainstream current flow. We show that the proposed design can convert energy at a higher efficiency as compared to both solid-state and available polyelectrolyte layer (PEL)-covered nanochannels. The same is true for the maximum power density at moderate and high concentration ratios including natural salt gradient conditions for which more than 50% increase is achievable. The maximum values achieved for efficiency and power density read 50.3% and 6.6 kW/m, respectively. Our results provide fundamental insights on strategizing variable-thickness polyelectrolyte layer grafting on the nanochannel interfaces, toward realizing high-performance osmotic power generators by altering the local ionic clouds alongside the grafted layers and enhancing the ionic mobility by inducing a driving potential gradient concomitantly. These findings open up a new strategy of efficient conversion of the power of the salinity difference of seawater and river water into electricity in a nanofluidic framework, surpassing the previously established limits of blue energy harvesting technologies.