Tengsuthiwat Jiratti, A Vinod, R Vijay, G Yashas Gowda T, Rangappa Sanjay Mavinkere, Siengchin Suchart
Department of Mechanical Engineering Technology, College of Industrial Technology (CIT), King Mongkut's University of Technology North Bangkok (KMUTNB), Bangkok, Thailand.
Natural Composites Research Group Lab, Department of Materials and Production Engineering, The Sirindhorn International Thai-German Graduate School of Engineering (TGGS), King Mongkut's University of Technology North Bangkok (KMUTNB), Bangkok, Thailand.
Heliyon. 2024 Apr 26;10(9):e30442. doi: 10.1016/j.heliyon.2024.e30442. eCollection 2024 May 15.
This study investigates tree bark fibers (FMB) as a sustainable alternative reinforcement for polymer composites. The Industrial Revolution marked the evolution of polymer composites with synthetic material reinforcement, leading to environmental concerns. Natural fibers have recently gained prominence as efficient alternatives for polymer composites. Despite numerous natural fibers being considered, ensuring a sustainable raw material source remains crucial. In this study, fibers were extracted from FMB and subjected to alkali treatment to evaluate their impact on physical, chemical, and thermal properties. Initially, the extracted fibers measured 253.80 ± 15 μm in diameter, reduced to 223.27 ± 12 μm post-alkali treatment. Chemical analysis showed an increase in cellulose content to 59.7 wt%, a 23.34 % improvement over untreated fibers (48.4 wt%). The crystalline index for untreated and treated fibers measured 80.20 % and 84.75 %, respectively, with no noticeable changes in the cellulose phase. Additionally, the crystalline size increased to 3.21 nm. Thermogravimetric analysis demonstrated enhanced stability of treated fibers up to 378.87 °C, while the kinetic activation energy remained constant at 64.76 kJ/mol for both the treated and the untreated fibers. The alkali treatment further improved surface roughness to 39.26, confirmed by scanning electron microscopic images. These findings highlight the potential of cellulose fibers from bark as a sustainable and environmentally friendly replacement for synthetic fibers in polymer composites. The enhanced physical properties and excellent thermal stability make them a promising choice for eco-conscious materials.
本研究调查了树皮纤维(FMB)作为聚合物复合材料可持续替代增强材料的情况。工业革命标志着聚合物复合材料随着合成材料增强剂的发展而演变,这引发了环境问题。天然纤维最近作为聚合物复合材料的有效替代品而受到关注。尽管考虑了众多天然纤维,但确保可持续的原材料来源仍然至关重要。在本研究中,从FMB中提取纤维并进行碱处理,以评估其对物理、化学和热性能的影响。最初,提取的纤维直径为253.80±15μm,碱处理后减小至223.27±12μm。化学分析表明纤维素含量增加到59.7wt%,比未处理纤维(48.4wt%)提高了23.34%。未处理和处理后纤维的结晶指数分别为80.20%和84.75%,纤维素相无明显变化。此外,结晶尺寸增加到3.21nm。热重分析表明处理后纤维在高达378.87°C时稳定性增强,而处理和未处理纤维的动力学活化能均保持在64.76kJ/mol不变。扫描电子显微镜图像证实碱处理进一步将表面粗糙度提高到39.26。这些发现突出了树皮纤维素纤维作为聚合物复合材料中合成纤维的可持续且环保替代品的潜力。增强的物理性能和优异的热稳定性使其成为注重环保材料的有前景选择。