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用于废水处理的银掺杂氧化锌/氧化镁纳米复合材料的绿色合成及其细胞毒性特性研究

Green synthesis of silver doped zinc oxide/magnesium oxide nanocomposite for waste water treatment and examination of their cytotoxicity properties.

作者信息

Shekofteh Narm Toktam, Hamidinezhad Habib, Sabouri Zahra, Darroudi Majid

机构信息

Department of Physics, Faculty of Basic Sciences, University of Mazandaran, Babolsar, Iran.

Nanobiotechnology Research Group, University of Mazandaran, Babolsar, Iran.

出版信息

Heliyon. 2024 Apr 25;10(9):e30374. doi: 10.1016/j.heliyon.2024.e30374. eCollection 2024 May 15.

Abstract

This research attempted to prepare silver-doped zinc oxide/magnesium oxide nanocomposite (Ag-doped ZnO/MgO-NCP) using plant extract. The synthesized NCP was investigated by X-ray diffraction analysis (XRD), Fourier Transform Infrared (FT-IR), Field Emission Scanning Electron Microscope (FESEM), Energy dispersive X-ray spectroscopy (EDX), Mapping, and UV-Visible analyses. The XRD data displayed cubic crystal structures for silver & magnesium oxide and a hexagonal framework for zinc oxide. Also, FESEM and PSA images of NCP pointed out, that the average size of the spherical morphology is about 10-16 nm, while the analysis of EDX confirmed the attendance of Zn, Mg, Ag, and O elements. Under UVA light, we tested the photocatalytic activity of NCP to the degradation of Methylene blue (MB) and Rhodamine B (RhB) dyes in various temperatures (400, 500, and 600 °C). The results of the photocatalytic test displayed that the degradation percentage of MB dye in pH = 9, nanocomposite amount ∼30 mg, and dye concentration ∼1 × 10  M was about 98 %. We also evaluated the cytotoxicity of nanocomposite on cancer CT-26 cell line through the MTT method and obtained an IC value of 250 μg/mL.

摘要

本研究尝试使用植物提取物制备银掺杂氧化锌/氧化镁纳米复合材料(Ag掺杂的ZnO/MgO-NCP)。通过X射线衍射分析(XRD)、傅里叶变换红外光谱(FT-IR)、场发射扫描电子显微镜(FESEM)、能量色散X射线光谱(EDX)、图谱分析和紫外可见分析对合成的纳米复合材料进行了研究。XRD数据显示银和氧化镁为立方晶体结构,氧化锌为六方结构。此外,纳米复合材料的FESEM和PSA图像表明,球形形态的平均尺寸约为10-16纳米,而EDX分析证实了锌、镁、银和氧元素的存在。在UVA光下,我们测试了纳米复合材料在不同温度(400、500和600℃)下对亚甲基蓝(MB)和罗丹明B(RhB)染料降解的光催化活性。光催化测试结果表明,在pH = 9、纳米复合材料用量约30毫克、染料浓度约1×10 摩尔时,MB染料的降解率约为98%。我们还通过MTT法评估了纳米复合材料对癌症CT-26细胞系的细胞毒性,获得的IC值为250微克/毫升。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a7e6/11079111/3a01d92b9f34/ga1.jpg

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