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探索1-酰基-3-取代硫脲的化学、结构、配位及多样应用的最新趋势:综述

Exploring the latest trends in chemistry, structure, coordination, and diverse applications of 1-acyl-3-substituted thioureas: a comprehensive review.

作者信息

Ullah Sayyed Aqib, Saeed Aamer, Azeem Muhammad, Haider Mian Bilal, Erben Mauricio F

机构信息

Department of Chemistry, Quaid-i-Azam University Islamabad 45320 Pakistan

Departamento de Química, CEQUINOR (UNLP, CONICET-CCT La Plata), Facultad de Ciencias Exactas, Universidad Nacional de La Plata Bv. 120 1465 La Plata 1900 Argentina.

出版信息

RSC Adv. 2024 Jun 5;14(25):18011-18063. doi: 10.1039/d4ra02567a. eCollection 2024 May 28.

DOI:10.1039/d4ra02567a
PMID:38847003
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11155445/
Abstract

Acyl thioureas represent a privileged moiety with vast potential applicability across diverse fields, making them the subject of extensive research efforts. The inherent flexibility of thiourea facilitates the synthesis of a wide range of core structures with diverse functionalities and properties. The distinctive presence of hard and soft donor sites renders acyl thioureas inclined to act as versatile ligands, thereby engendering a diverse array of metal complexes incorporating acyl thiourea as a pivotal ligand. Extensive investigations into the synthesized acyl thioureas and their derivatives have culminated in the elucidation of their substantial potential across a spectrum of applications, spanning biological activities, materials chemistry, catalysis, and beyond. This literature review represents a continuation of our ongoing endeavor to compile comprehensive data on research endeavors concerning acyl thioureas over the past two years.

摘要

酰基硫脲是一种具有特殊结构的基团,在各个领域具有广泛的潜在应用价值,因此成为了广泛研究的对象。硫脲固有的灵活性有助于合成具有各种功能和性质的多种核心结构。硬供体和软供体位点的独特存在使酰基硫脲倾向于作为多功能配体,从而产生了一系列以酰基硫脲作为关键配体的金属配合物。对合成的酰基硫脲及其衍生物的广泛研究最终阐明了它们在一系列应用中的巨大潜力,包括生物活性、材料化学、催化等领域。这篇文献综述是我们持续努力的延续,旨在汇编过去两年中有关酰基硫脲研究工作的全面数据。

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