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解锁潜力:技术木质素在多种应用中的演变角色和克服挑战。

Unlocking the potential: Evolving role of technical lignin in diverse applications and overcoming challenges.

机构信息

Division of Bioresource Technology, School of Industrial Technology, Universiti Sains Malaysia, Gelugor 11800, Malaysia.

Division of Bioresource Technology, School of Industrial Technology, Universiti Sains Malaysia, Gelugor 11800, Malaysia; Green Biopolymer, Coatings and Packaging Cluster, School of Industrial Technology, Universiti Sains Malaysia, Minden, 11800, Malaysia.

出版信息

Int J Biol Macromol. 2024 Aug;274(Pt 2):133506. doi: 10.1016/j.ijbiomac.2024.133506. Epub 2024 Jun 27.

Abstract

Recent advancements have transformed lignin from a byproduct into a valuable raw material for polymers, dyes, adhesives, and fertilizers. However, its structural heterogeneity, variable reactive group content, impurities, and high extraction costs pose challenges to industrial-scale adoption. Efficient separation technologies and selective bond cleavage are crucial. Advanced pretreatment methods have enhanced lignin purity and reduced contamination, while novel catalytic techniques have improved depolymerization efficiency and selectivity. This review compares catalytic depolymerization methodologies, highlighting their advantages and disadvantages, and noting challenges in comparing yield values due to variations in isolation methods and lignin sources. Recognizing "technical lignin" from pulping processes, the review emphasizes its diverse applications and the necessity of understanding its structural characteristics. Emerging trends focus on bio-based functional additives and nanostructured lignin materials, promising enhanced properties and functionalities. Innovations open possibilities in sustainable agriculture, high-performance foams and composites, and advanced medical applications like drug delivery and wound healing. Leveraging lignin's biocompatibility, abundance, and potential for high-value applications, it can significantly contribute to sustainable material development across various industries. Continuous research in bio-based additives and nanostructured materials underscores lignin's potential to revolutionize material science and promote environmentally friendly industrial applications.

摘要

最近的进展将木质素从一种副产品转变为聚合物、染料、胶粘剂和肥料的有价值的原料。然而,其结构异质性、可变反应基团含量、杂质和高提取成本对工业规模的采用构成了挑战。高效的分离技术和选择性键断裂至关重要。先进的预处理方法提高了木质素的纯度并减少了污染,而新型催化技术则提高了解聚效率和选择性。本综述比较了催化解聚方法,强调了它们的优缺点,并注意到由于分离方法和木质素来源的变化,比较产率值存在挑战。认识到制浆过程中的“技术木质素”,强调了其多样化的应用,以及了解其结构特征的必要性。新兴趋势侧重于基于生物的功能性添加剂和纳米结构木质素材料,有望提高性能和功能。创新为可持续农业、高性能泡沫和复合材料以及药物输送和伤口愈合等先进的医疗应用开辟了可能性。利用木质素的生物相容性、丰富度和高附加值应用的潜力,它可以为各个行业的可持续材料发展做出重大贡献。生物基添加剂和纳米结构材料的持续研究强调了木质素在推动材料科学革命和促进环保型工业应用方面的潜力。

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