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用于混合离子电容器的功能化生物质衍生多孔碳及其复合材料的最新进展

Recent Advances in Functionalized Biomass-Derived Porous Carbons and their Composites for Hybrid Ion Capacitors.

作者信息

George Nithya S, Singh Gurwinder, Bahadur Rohan, Kumar Prashant, Ramadass Kavitha, Sathish C I, Benzigar Mercy, Sajan Davidson, Aravind Arun, Vinu Ajayan

机构信息

Global Innovative Centre for Advanced Nanomaterials (GICAN), College of Engineering, Science and Environment (CESE), School of Engineering, The University of Newcastle, Callaghan, NSW, 2308, Australia.

Centre for Advanced Functional Materials, Department of Physics, Bishop Moore College, Mavelikara, Alappuzha, Kerala, 690110, India.

出版信息

Adv Sci (Weinh). 2024 Sep;11(35):e2406235. doi: 10.1002/advs.202406235. Epub 2024 Jul 19.

DOI:10.1002/advs.202406235
PMID:39031008
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11425278/
Abstract

Hybrid ion capacitors (HICs) have aroused extreme interest due to their combined characteristics of energy and power densities. The performance of HICs lies hidden in the electrode materials used for the construction of battery and supercapacitor components. The hunt is always on to locate the best material in terms of cost-effectiveness and overall optimized performance characteristics. Functionalized biomass-derived porous carbons (FBPCs) possess exquisite features including easy synthesis, wide availability, high surface area, large pore volume, tunable pore size, surface functional groups, a wide range of morphologies, and high thermal and chemical stability. FBPCs have found immense use as cathode, anode and dual electrode materials for HICs in the recent literature. The current review is designed around two main concepts which include the synthesis and properties of FBPCs followed by their utilization in various types of HICs. Among monovalent HICs, lithium, sodium, and potassium, are given comprehensive attention, whereas zinc is the only multivalent HIC that is focused upon due to corresponding literature availability. Special attention is also provided to the critical factors that govern the performance of HICs. The review concludes by providing feasible directions for future research in various aspects of FBPCs and their utilization in HICs.

摘要

混合离子电容器（HICs）因其能量密度和功率密度的综合特性而引起了极大的关注。HICs的性能隐藏在用于构建电池和超级电容器组件的电极材料中。人们一直在寻找在成本效益和整体优化性能方面最佳的材料。功能化生物质衍生多孔碳（FBPCs）具有诸多优良特性，包括易于合成、来源广泛、高比表面积、大孔体积、可调孔径、表面官能团、多种形态以及高热稳定性和化学稳定性。在最近的文献中，FBPCs作为HICs的阴极、阳极和双电极材料有广泛应用。当前的综述围绕两个主要概念展开，包括FBPCs的合成与性质，以及它们在各类HICs中的应用。在单价HICs中，锂、钠和钾受到了全面关注，而由于相关文献的可得性，锌是唯一被关注的多价HIC。还特别关注了影响HICs性能的关键因素。综述最后为FBPCs的各个方面及其在HICs中的应用提供了未来研究的可行方向。

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