• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

钠离子电池中NaNiZr(PO)的速率依赖性稳定性和电化学行为

Rate-Dependent Stability and Electrochemical Behavior of NaNiZr(PO) in Sodium-Ion Batteries.

作者信息

Tayoury Marwa, Chari Abdelwahed, Aqil Mohamed, Idrissi Adil Sghiouri, El Bendali Ayoub, Alami Jones, Tamraoui Youssef, Dahbi Mouad

机构信息

Materials Science, Energy, and Nano-engineering Department, Mohammed VI Polytechnic University, Ben Guerir 43150, Morocco.

出版信息

Nanomaterials (Basel). 2024 Jul 16;14(14):1204. doi: 10.3390/nano14141204.

DOI:10.3390/nano14141204
PMID:39057880
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11279984/
Abstract

In advancing sodium-ion battery technology, we introduce a novel application of NaNiZr(PO) with a NASICON structure as an anode material. This research unveils, for the first time, its exceptional ability to maintain high specific capacity and unprecedented cycle stability under extreme current densities up to 1000 mA·g, within a low voltage window of 0.01-2.5 V. The core of our findings lies in the material's remarkable capacity retention and stability, which is a leap forward in addressing long-standing challenges in energy storage. Through cutting-edge in situ/operando X-ray diffraction analysis, we provide a perspective on the structural evolution of NaNiZr(PO) during operation, offering deep insights into the mechanisms that underpin its superior performance.

摘要

在推进钠离子电池技术的过程中,我们引入了一种具有NASICON结构的新型NaNiZr(PO)作为阳极材料的应用。这项研究首次揭示了其在高达1000 mA·g的极端电流密度下,在0.01 - 2.5 V的低电压窗口内保持高比容量和前所未有的循环稳定性的卓越能力。我们研究结果的核心在于该材料出色的容量保持率和稳定性,这在解决储能领域长期存在的挑战方面向前迈出了一大步。通过前沿的原位/操作X射线衍射分析,我们对NaNiZr(PO)在运行过程中的结构演变提供了一个视角,深入洞察了支撑其卓越性能的机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/02aab7d9d370/nanomaterials-14-01204-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/18dd7645481b/nanomaterials-14-01204-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/bb0cb6ffda21/nanomaterials-14-01204-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/a66a1ffa2957/nanomaterials-14-01204-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/4c52b922a06d/nanomaterials-14-01204-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/ddcc6b2dad55/nanomaterials-14-01204-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/02aab7d9d370/nanomaterials-14-01204-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/18dd7645481b/nanomaterials-14-01204-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/bb0cb6ffda21/nanomaterials-14-01204-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/a66a1ffa2957/nanomaterials-14-01204-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/4c52b922a06d/nanomaterials-14-01204-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/ddcc6b2dad55/nanomaterials-14-01204-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15d3/11279984/02aab7d9d370/nanomaterials-14-01204-g006.jpg

相似文献

1
Rate-Dependent Stability and Electrochemical Behavior of NaNiZr(PO) in Sodium-Ion Batteries.钠离子电池中NaNiZr(PO)的速率依赖性稳定性和电化学行为
Nanomaterials (Basel). 2024 Jul 16;14(14):1204. doi: 10.3390/nano14141204.
2
NASICON-Structured NaTi2(PO4)3@C Nanocomposite as the Low Operation-Voltage Anode Material for High-Performance Sodium-Ion Batteries.NASICON 结构的 NaTi2(PO4)3@C 纳米复合材料作为低工作电压的钠离子电池高性能负极材料。
ACS Appl Mater Interfaces. 2016 Jan 27;8(3):2238-46. doi: 10.1021/acsami.5b11003. Epub 2016 Jan 12.
3
NaNbV(PO): Multielectron NASICON-Type Anode Material for Na-Ion Batteries with Excellent Rate Capability.NaNbV(PO): 用于钠离子电池的多电子 NASICON 型正极材料,具有优异的倍率性能。
ACS Appl Mater Interfaces. 2023 Jun 28;15(25):30272-30280. doi: 10.1021/acsami.3c04576. Epub 2023 Jun 17.
4
NASICON-Type MgTi(PO) Negative Electrode Material Exhibits Different Electrochemical Energy Storage Mechanisms in Na-Ion and Li-Ion Batteries.NASICON 型 MgTi(PO) 负极材料在钠离子和锂离子电池中表现出不同的电化学储能机制。
ACS Appl Mater Interfaces. 2017 Feb 8;9(5):4709-4718. doi: 10.1021/acsami.6b14196. Epub 2017 Jan 30.
5
Symmetric Sodium-Ion Battery Based on Dual-Electron Reactions of NASICON-Structured NaMnTi(PO) Material.基于NASICON结构的NaMnTi(PO)材料双电子反应的对称钠离子电池
ACS Appl Mater Interfaces. 2020 Jul 8;12(27):30328-30335. doi: 10.1021/acsami.0c05784. Epub 2020 Jun 25.
6
Na Superionic Conductor-Type TiNb(PO) Anode with High Energy Density and Long Cycle Life Enables Aqueous Alkaline-Ion Batteries.具有高能量密度和长循环寿命的超离子导体型 TiNb(PO) 正极助力水系碱性离子电池。
ACS Appl Mater Interfaces. 2019 Oct 30;11(43):39757-39764. doi: 10.1021/acsami.9b10671. Epub 2019 Oct 16.
7
Preparation of Nb Doped NaV(PO) Cathode Material for Sodium Ion Batteries.用于钠离子电池的铌掺杂NaV(PO)正极材料的制备
Materials (Basel). 2024 Jun 3;17(11):2697. doi: 10.3390/ma17112697.
8
Understanding the Structural Phase Transitions in Na V (PO ) Symmetrical Sodium-Ion Batteries Using Synchrotron-Based X-Ray Techniques.利用基于同步加速器的X射线技术理解NaV(PO)对称钠离子电池中的结构相变
Small Methods. 2022 Feb;6(2):e2100888. doi: 10.1002/smtd.202100888. Epub 2021 Dec 16.
9
In Situ Electrochemical Coating Mechanism of NASICON-Structured AgTi(PO) for Sodium-Ion Batteries.用于钠离子电池的NASICON结构AgTi(PO)的原位电化学涂层机制
ACS Appl Mater Interfaces. 2020 Feb 5;12(5):5932-5938. doi: 10.1021/acsami.9b20539. Epub 2020 Jan 22.
10
Ultra-Fast-Charging, Long-Duration, and Wide-Temperature-Range Sodium Storage Enabled by Multiwalled Carbon Nanotube-Hybridized Biphasic Polyanion-Type Phosphate Cathode Materials.多壁碳纳米管杂化双相聚阴离子型磷酸盐阴极材料实现的超快充电、长续航和宽温度范围的钠存储
ACS Appl Mater Interfaces. 2024 Jul 10;16(27):34819-34829. doi: 10.1021/acsami.4c02565. Epub 2024 Jun 26.

引用本文的文献

1
Advances in Nanomaterials for Energy Conversion and Environmental Catalysis.用于能量转换与环境催化的纳米材料进展
Nanomaterials (Basel). 2024 Nov 27;14(23):1902. doi: 10.3390/nano14231902.

本文引用的文献

1
Multiwalled carbon nanotube network connected MgTi(PO) composites to improve sodium storage performance.多壁碳纳米管网络连接的MgTi(PO)复合材料以改善储钠性能。
RSC Adv. 2022 Dec 14;12(55):35756-35762. doi: 10.1039/d2ra06449a. eCollection 2022 Dec 12.
2
High-Energy Batteries: Beyond Lithium-Ion and Their Long Road to Commercialisation.高能电池:超越锂离子电池及其漫长的商业化之路
Nanomicro Lett. 2022 Apr 6;14(1):94. doi: 10.1007/s40820-022-00844-2.
3
Low-Cost and High-Performance Hard Carbon Anode Materials for Sodium-Ion Batteries.
用于钠离子电池的低成本高性能硬碳负极材料
ACS Omega. 2017 Apr 27;2(4):1687-1695. doi: 10.1021/acsomega.7b00259. eCollection 2017 Apr 30.
4
NaMnZr(PO): A High-Voltage Cathode for Sodium Batteries.NaMnZr(PO):一种用于钠电池的高压阴极材料。
J Am Chem Soc. 2018 Dec 26;140(51):18192-18199. doi: 10.1021/jacs.8b11388. Epub 2018 Dec 12.
5
Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries.用于先进钠离子电池的 NASICON 型电极材料的挑战和展望。
Adv Mater. 2017 Dec;29(48). doi: 10.1002/adma.201700431. Epub 2017 Jun 19.
6
Phosphate Framework Electrode Materials for Sodium Ion Batteries.用于钠离子电池的磷酸盐框架电极材料
Adv Sci (Weinh). 2017 Jan 18;4(5):1600392. doi: 10.1002/advs.201600392. eCollection 2017 May.
7
Sodium-ion batteries: present and future.钠离子电池:现状与未来。
Chem Soc Rev. 2017 Jun 19;46(12):3529-3614. doi: 10.1039/c6cs00776g.
8
Polyanion-Type Electrode Materials for Sodium-Ion Batteries.用于钠离子电池的聚阴离子型电极材料。
Adv Sci (Weinh). 2017 Jan 25;4(3):1600275. doi: 10.1002/advs.201600275. eCollection 2017 Mar.
9
NASICON-Structured Materials for Energy Storage.NASICON 结构材料在储能领域的应用。
Adv Mater. 2017 May;29(20). doi: 10.1002/adma.201601925. Epub 2017 Feb 21.
10
NASICON-Type MgTi(PO) Negative Electrode Material Exhibits Different Electrochemical Energy Storage Mechanisms in Na-Ion and Li-Ion Batteries.NASICON 型 MgTi(PO) 负极材料在钠离子和锂离子电池中表现出不同的电化学储能机制。
ACS Appl Mater Interfaces. 2017 Feb 8;9(5):4709-4718. doi: 10.1021/acsami.6b14196. Epub 2017 Jan 30.