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使用香豆素衍生荧光化学传感器检测汞(Hg):2015年至2023年的直观发展历程

Mercury (Hg) Sensing Using Coumarin-Derived Fluorescent Chemo-Sensors: An Intuitive Development from 2015 to 2023.

作者信息

Jaswal Ansh, Swami Suman, Saini Ajay

机构信息

Department of Chemistry, Chandigarh University, NH-05, Ludhiana - Chandigarh State Hwy, Mohali, Punjab, India, 140413.

Central Analytical Facilities, Manipal University Jaipur, Jaipur-Ajmer Express Highway, Dehmi Kalan, Near GVK Toll Plaza, Jaipur, Rajasthan, India, 303007.

出版信息

J Fluoresc. 2024 Aug 10. doi: 10.1007/s10895-024-03889-1.

DOI:10.1007/s10895-024-03889-1
PMID:39126606
Abstract

Mercury is known as a highly toxic metal that is poisonous even if present in a trace amount. Generally, it enters in the food chain (especially fish) and water resources via different pathways and leads to harmful effects. Owing to the detrimental nature of the metal, traditionally several methods were employed by researchers for regular monitoring of the mercury metal ions. However, these methods are associated with many limitations like high cost of technical expertise, and intricacy of the detection procedure. So, using these methods to detect mercury ions in real time is challenging. Therefore, in recent years fluorescent-based analytical tools emerged rapidly. Among the various fluorescent organic scaffolds, coumarin has been scorching, owing to quick response, light stability, high sensitivity, good selectivity, excellent fluorescence intensity, and fluorescence quantum yield. This review provides a deep dive into the coumarin-derived chemo-sensors development throughout 2015-2023. We anticipate that the review will assist to broad scientific community as a reference document to design more interesting sensors.

摘要

汞是一种剧毒金属,即使微量存在也具有毒性。一般来说,它通过不同途径进入食物链(尤其是鱼类)和水资源,并产生有害影响。由于这种金属的有害性质,研究人员传统上采用了几种方法来定期监测汞金属离子。然而,这些方法存在许多局限性,如技术专业知识成本高、检测程序复杂。因此,使用这些方法实时检测汞离子具有挑战性。因此,近年来基于荧光的分析工具迅速涌现。在各种荧光有机支架中,香豆素因其响应迅速、光稳定性好、灵敏度高、选择性好、荧光强度优异和荧光量子产率高而备受关注。本综述深入探讨了2015年至2023年香豆素衍生的化学传感器的发展。我们预计,这篇综述将作为一份参考文件,帮助广大科学界设计出更有趣的传感器。

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本文引用的文献

1
A facile synthesis of a novel 4-hydroxyl-3-azo coumarin based colorimetric probes for detecting Hg and a fluorescence turn-off response of 3CBD to Fe in aqueous environment.一种用于检测汞的新型4-羟基-3-偶氮香豆素比色探针的简便合成方法以及3CBD在水环境中对铁的荧光猝灭响应。
RSC Adv. 2023 Oct 30;13(45):31541-31553. doi: 10.1039/d3ra04047j. eCollection 2023 Oct 26.
2
Highly selective and sensitive detection of Hg by a novel fluorescent probe with dual recognition sites.基于双识别位点的新型荧光探针高选择性和高灵敏度检测汞。
Spectrochim Acta A Mol Biomol Spectrosc. 2023 Apr 15;291:122379. doi: 10.1016/j.saa.2023.122379. Epub 2023 Jan 18.
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A Coumarin-azo Derived Colorimetric Chemosensor for Hg Detection in Organic and Aqueous Media and its Extended Real-world Applications.
一种香豆素偶氮衍生的比色化学传感器,用于有机和水相介质中的 Hg 检测及其扩展的实际应用。
J Fluoresc. 2023 Jan;33(1):267-285. doi: 10.1007/s10895-022-03065-3. Epub 2022 Nov 21.
4
Fluorescence Variation in Selective Sensing of Hgand Cu Ions By Coumarin-xanthene Fused Optical Probe.香豆素-呫吨杂合体荧光探针选择性识别 Hg2+和 Cu2+离子的荧光变化。
J Fluoresc. 2022 Nov;32(6):2379-2393. doi: 10.1007/s10895-022-03030-0. Epub 2022 Oct 1.
5
A smartphone readout device for portable and sensitive estimation of Hg via coumarin-modified paper.一种智能手机读出设备,可通过香豆素修饰纸进行便携式和灵敏的汞估算。
Talanta. 2023 Jan 15;252:123849. doi: 10.1016/j.talanta.2022.123849. Epub 2022 Aug 23.
6
Synthesis and application of a novel polyurethane nanoemulsion bearing coumarin derivative as a "turn-on" fluorescence sensor toward Hg.新型含香豆素衍生物的聚氨酯纳米乳液的合成与应用作为一种“开-关”型荧光传感器用于 Hg.
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Nov 15;281:121612. doi: 10.1016/j.saa.2022.121612. Epub 2022 Jul 9.
7
Synthesis and application of coumarin fluorescence probes.香豆素荧光探针的合成与应用
RSC Adv. 2020 Mar 17;10(18):10826-10847. doi: 10.1039/c9ra10290f. eCollection 2020 Mar 11.
8
A novel coumarin-based colorimetric and fluorescent probe for detecting increasing concentrations of Hg and .一种用于检测汞离子浓度不断增加的新型香豆素基比色和荧光探针。 (注:原文中“Hg and.”表述不完整,推测可能是“Hg²⁺”之类,这里按合理推测翻译)
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9
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Anal Chim Acta. 2022 Feb 8;1193:339378. doi: 10.1016/j.aca.2021.339378. Epub 2021 Dec 18.
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A novel coumarin-benzopyrylium based near-infrared fluorescent probe for Hg and its practical applications.一种基于香豆素-苯并吡喃鎓的新型汞近红外荧光探针及其实际应用。
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Feb 15;267(Pt 1):120527. doi: 10.1016/j.saa.2021.120527. Epub 2021 Oct 30.