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立方结构的锌铁氧体有序地掺入多孔石墨烯片层中,作为电化学检测多菌灵的选择性电催化剂。

Cubic structured zinc ferrite methodically incorporated into porous graphene sheets as a selective Electrocatalyst for electrochemical detection of Carbendazim.

机构信息

Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No. 1, Section 3, Chung-Hsiao East Road, Taipei 106, Taiwan.

Department of Materials, Imperial College London, London SW7 2AZ, United Kingdom.

出版信息

Food Chem. 2024 Dec 15;461:140892. doi: 10.1016/j.foodchem.2024.140892. Epub 2024 Aug 15.

Abstract

Carbendazim (CBZ) insecticides have been widely employed, raising serious concerns about their impacts on human health and the environment. A facile hydrothermal technique was used to prepare a zinc ferrite (ZnFe₂O₄) combined with porous graphene oxide (PGO) as a nanocomposite for selective CBZ detection. The ZnFe₂O₄/PGO nanocomposite was then used to modify a glassy carbon electrode (GCE), an affordable platform for CBZ detection. Various spectroscopic techniques were employed to confirm the nanomaterial. The electrochemical properties were further investigated using cyclic voltammetry (CV), differential pulse voltammetry (DPV), and electrochemical impedance spectroscopy (EIS). The ZnFe₂O₄/PGO nanocomposite modified the glassy carbon electrode surface for CBZ detection. A broad linear response range of 0.0039 to 200 μM, high sensitivity (2.184 μAμM cm), a low detection limit of 0.0013 μM, outstanding stability, repeatability, and practical applicability are the intriguing qualities of the ZnFe₂O₄/PGO-modified electrode for CBZ detection.

摘要

多菌灵(CBZ)杀虫剂已被广泛应用,但人们对其对人类健康和环境的影响表示严重关切。本研究采用简便的水热技术制备了一种锌铁氧体(ZnFe₂O₄)与多孔氧化石墨烯(PGO)结合的纳米复合材料,用于选择性检测 CBZ。然后,将 ZnFe₂O₄/PGO 纳米复合材料用于修饰玻碳电极(GCE),这是一种用于 CBZ 检测的廉价平台。采用各种光谱技术对纳米材料进行了确认。进一步通过循环伏安法(CV)、差分脉冲伏安法(DPV)和电化学阻抗谱(EIS)研究了电化学性质。ZnFe₂O₄/PGO 纳米复合材料修饰玻碳电极表面,用于 CBZ 检测。ZnFe₂O₄/PGO 修饰电极对 CBZ 检测具有宽线性响应范围(0.0039 至 200 μM)、高灵敏度(2.184 μAμM cm)、低检测限(0.0013 μM)、出色的稳定性、重复性和实际适用性。

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