Li Tiejun, Lu Ruiyu, Cao Yuankui, Liu Bicheng, Fu Ao, Liu Bin
State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China.
Materials (Basel). 2024 Aug 12;17(16):4010. doi: 10.3390/ma17164010.
Graphene/copper composites are promising in electronic and energy fields due to their superior conductivity, but microstructure control during thermal mechanical processing (TMP) remains a crucial issue for the manufacturing of high-performance graphene/copper composites. In this study, the hot deformation behavior of graphene/copper composites was investigated by isothermal compression tests at deformation temperatures of 700850 °C and strain rates of 0.0110 s, and a constitutive equation based on the Arrhenius model and hot processing map was established. Results demonstrate that the deformation mechanism of the graphene/copper composites mainly involves dynamic recrystallization (DRX), and such DRX-mediated deformation behavior can be accurately described by the established Arrhenius model. In addition, it was found that the strain rate has a stronger impact on the DRX grain size than the deformation temperature. The optimum deformation temperature and strain rate were determined to be 800 °C and 1 s, respectively, with which a uniform microstructure with fine grains can be obtained.
石墨烯/铜复合材料因其优异的导电性在电子和能源领域具有广阔前景,但热机械加工(TMP)过程中的微观结构控制仍是制造高性能石墨烯/铜复合材料的关键问题。本研究通过在700850℃变形温度和0.0110s应变率下的等温压缩试验,研究了石墨烯/铜复合材料的热变形行为,并建立了基于Arrhenius模型和热加工图的本构方程。结果表明,石墨烯/铜复合材料的变形机制主要涉及动态再结晶(DRX),且这种由DRX介导的变形行为可以通过所建立的Arrhenius模型准确描述。此外,发现应变率对DRX晶粒尺寸的影响比变形温度更强。确定最佳变形温度和应变率分别为800℃和1s,由此可获得具有细晶粒的均匀微观结构。