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石墨烯/铜复合材料的热变形行为与微观结构演变

Hot Deformation Behavior and Microstructure Evolution of a Graphene/Copper Composite.

作者信息

Li Tiejun, Lu Ruiyu, Cao Yuankui, Liu Bicheng, Fu Ao, Liu Bin

机构信息

State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China.

出版信息

Materials (Basel). 2024 Aug 12;17(16):4010. doi: 10.3390/ma17164010.

Abstract

Graphene/copper composites are promising in electronic and energy fields due to their superior conductivity, but microstructure control during thermal mechanical processing (TMP) remains a crucial issue for the manufacturing of high-performance graphene/copper composites. In this study, the hot deformation behavior of graphene/copper composites was investigated by isothermal compression tests at deformation temperatures of 700850 °C and strain rates of 0.0110 s, and a constitutive equation based on the Arrhenius model and hot processing map was established. Results demonstrate that the deformation mechanism of the graphene/copper composites mainly involves dynamic recrystallization (DRX), and such DRX-mediated deformation behavior can be accurately described by the established Arrhenius model. In addition, it was found that the strain rate has a stronger impact on the DRX grain size than the deformation temperature. The optimum deformation temperature and strain rate were determined to be 800 °C and 1 s, respectively, with which a uniform microstructure with fine grains can be obtained.

摘要

石墨烯/铜复合材料因其优异的导电性在电子和能源领域具有广阔前景,但热机械加工(TMP)过程中的微观结构控制仍是制造高性能石墨烯/铜复合材料的关键问题。本研究通过在700850℃变形温度和0.0110s应变率下的等温压缩试验,研究了石墨烯/铜复合材料的热变形行为,并建立了基于Arrhenius模型和热加工图的本构方程。结果表明,石墨烯/铜复合材料的变形机制主要涉及动态再结晶(DRX),且这种由DRX介导的变形行为可以通过所建立的Arrhenius模型准确描述。此外,发现应变率对DRX晶粒尺寸的影响比变形温度更强。确定最佳变形温度和应变率分别为800℃和1s,由此可获得具有细晶粒的均匀微观结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9455/11356280/45c0cf54977e/materials-17-04010-g001.jpg

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