Experimental comparison of the effects of the two designed probes for exfoliation of graphene by sonication.

In the present research, comparative simulation and experimental investigation were carried out for two different probes to improve the efficiency and quality of few-layer graphene utilizing liquid-phase exfoliation. Two differently designed shaped probes are fabricated for this study, i.e., a simple probe and a stepped probe. The acoustic pressure distribution in the vessel is simulated for both probes at different output powers. In the experiment, both probes exfoliate graphite powder in a mixture of deionized water and ethanol. Different sonication times and output power were studied for different pulse modes. The graphene layers were characterized using Ultraviolet-visible spectroscopy (UV‒Vis), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and Raman Microscope. The simulation shows that the total displacement on the tip of the stepped probe is 5.7% greater than that of the simple probe. Also, the pressure difference produced by the stepped probe is 9.15 × 10 pa compared to the pressure difference of the simple probe which is 8.23 × 10 pa. Consequently, the stepped probe was more effective in exfoliating graphene. The experimental results show that the absorbance peak in the stepped probe is approximately 32% greater than the absorbance peak in the simple probe with the same output power. Also, the graphene with better quality is produced with the stepped probe compared to the simple probe, which verifies the simulation findings. Additionally, the optimum output power, pulse duration, and sonication time to produce graphene with less time and energy consumption are obtained. The best graphene flakes were obtained via sonication with a pulse duration of 0.7 s, an output power of 282 W, and a sonication time of 45 min using a stepped probe. UV-Vis., SEM and TEM analysis show increases in quantity and quality of the exfoliated flakes. These results are approved by the peak ratio of I/I around 1 in Raman spectra revealed the production of the few-layer graphene by the simple probe and the bilayer graphene by the stepped probe. So, this method is suitable for the production of graphene flakes from graphite in suitable quantity and quality.