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关于氢气生产、储存及应用的全面综述。

A comprehensive review on hydrogen production, storage, and applications.

作者信息

Gunathilake Chamila, Soliman Ibrahim, Panthi Dhruba, Tandler Peter, Fatani Omar, Ghulamullah Noman Alias, Marasinghe Dinesh, Farhath Mohamed, Madhujith Terrence, Conrad Kirt, Du Yanhai, Jaroniec Mietek

机构信息

Department of Applied Engineering & Technology, College of Aeronautics and Engineering, Kent State University, Kent, OH, 44242, USA.

Department of Chemistry & Biochemistry, Kent State University, Kent, OH, 44242, USA.

出版信息

Chem Soc Rev. 2024 Nov 12;53(22):10900-10969. doi: 10.1039/d3cs00731f.

Abstract

The transformation from combustion-based to renewable energy technologies is of paramount importance due to the rapid depletion of fossil fuels and the dramatic increase in atmospheric CO levels resulting from growing global energy demands. To achieve the Paris Agreement's long-term goal of carbon neutrality by 2050, the full implementation of clean and sustainable energy sources is essential. Consequently, there is an urgent demand for zero or low-carbon fuels with high energy density that can produce electricity and heat, power vehicles, and support global trade. This review presents the global motivation to reduce carbon dioxide by utilizing hydrogen technology, which is key to meeting future energy demands. It discusses the basic properties of hydrogen and its application in both prototype and large-scale efficient technologies. Hydrogen is a clean fuel and a versatile energy carrier; when used in fuel cells or combustion devices, the final product is water vapor. Hydrogen gas production methods are reviewed across renewable and non-renewable sources, with reaction processes categorized as green, blue, grey, black, pink, and turquoise, depending on the reaction pathway and CO emissions management. This review covers the applications of hydrogen technology in petroleum refining, chemical and metrological production, hydrogen fuel cell electric vehicles (HFCEVs), backup power generation, and its use in transportation, space, and aeronautics. It assesses physical and material-based hydrogen storage methods, evaluating their feasibility, performance, and safety, and comparing HFCEVs with battery and gasoline vehicles from environmental and economic perspectives. Finally, the prospects and challenges associated with hydrogen production, handling, storage, transportation, and safety are also discussed.

摘要

由于化石燃料的迅速枯竭以及全球能源需求增长导致大气中二氧化碳水平急剧上升,从基于燃烧的能源技术向可再生能源技术的转变至关重要。为实现《巴黎协定》到2050年实现碳中和的长期目标,全面实施清洁和可持续能源至关重要。因此,迫切需要具有高能量密度的零碳或低碳燃料,这些燃料可用于发电和供热、为车辆提供动力以及支持全球贸易。本综述介绍了利用氢能技术减少二氧化碳排放的全球动机,这是满足未来能源需求的关键。它讨论了氢的基本特性及其在原型和大规模高效技术中的应用。氢是一种清洁燃料和通用能源载体;当用于燃料电池或燃烧装置时,最终产物是水蒸气。本文综述了可再生和不可再生来源的氢气生产方法,根据反应途径和二氧化碳排放管理,将反应过程分为绿色、蓝色、灰色、黑色、粉色和蓝绿色。本综述涵盖了氢能技术在石油炼制、化工和计量生产、氢燃料电池电动汽车(HFCEV)、备用发电以及在交通运输、航天和航空领域的应用。它评估了基于物理和材料的储氢方法,评估了它们的可行性、性能和安全性,并从环境和经济角度将氢燃料电池电动汽车与电池和汽油车辆进行了比较。最后,还讨论了氢气生产、处理、储存、运输和安全方面的前景和挑战。

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