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用于从废水中自发捕获内分泌干扰化合物的金属氧化物纳米催化剂。

Metal-oxide nanocatalysts for spontaneous sequestration of endocrine-disrupting compounds from wastewater.

机构信息

Department of Chemistry, Faculty of Natural and Applied Sciences, Lead City University, Ibadan, Nigeria.

Department of Chemistry, Faculty of Natural and Applied Sciences, Lead City University, Ibadan, Nigeria.

出版信息

Chemosphere. 2024 Nov;367:143569. doi: 10.1016/j.chemosphere.2024.143569. Epub 2024 Oct 18.

Abstract

The quest for a good life, urbanization, and industrialization have led to the widespread distribution of endocrine-disrupting chemicals (EDCs) in water bodies through anthropogenic activities. This poses an imminent threat to both human and environmental health. In recent years, the utilization of advance materials for the removal of EDCs from wastewater has attracted a lot of attention. Metal-oxide nanocatalysts have emerged as promising candidates due to their high surface area, reactivity, and tunable properties, as well as enhanced surface properties such as mesoporous structures and hierarchical morphologies that allow for increased adsorption capacity, improved photocatalytic activity, and enhanced selectivity towards specific EDCs. As a result, they have shown extraordinary efficacy in removing a wide range of EDCs from aqueous solutions, including pharmaceuticals, agrochemicals, personal care items, and industrial chemicals. This study give insight into the unique physicochemical characteristics of metal-oxide nanocatalysts to effectively and efficiently remove harmful EDCs from wastewater. It also discussed the advances in the synthesis, and properties of metal-oxide nanocatalysts, and insight into understanding the fundamental mechanisms underlying the adsorption and degradation of EDCs on metal-oxide nanocatalysts using advanced characterization techniques such as spectroscopic analysis and electron microscopy. The findings of the study present metal-oxide nanocatalysts as a good candidate for the spontaneous sequestration of EDCs from wastewater is an intriguing approach to mitigating water pollution and safeguarding public health and the environment.

摘要

对美好生活的追求、城市化和工业化导致人为活动将内分泌干扰化学物质(EDCs)广泛分布在水体中。这对人类健康和环境健康构成了迫在眉睫的威胁。近年来,利用先进材料去除废水中的 EDCs 引起了广泛关注。由于具有高表面积、反应性和可调特性,以及增强的表面特性,如介孔结构和分级形态,金属氧化物纳米催化剂已成为有前途的候选物,这些特性可提高吸附能力、改善光催化活性,并提高对特定 EDCs 的选择性。因此,它们在从水溶液中去除各种 EDCs(包括药物、农药、个人护理用品和工业化学品)方面表现出非凡的功效。本研究深入了解了金属氧化物纳米催化剂的独特物理化学特性,以有效且高效地从废水中去除有害的 EDCs。它还讨论了金属氧化物纳米催化剂的合成和特性方面的进展,并深入了解了使用光谱分析和电子显微镜等先进表征技术,在金属氧化物纳米催化剂上 EDCs 的吸附和降解的基本机制。研究结果表明,金属氧化物纳米催化剂是从废水中自发螯合 EDCs 的良好候选物,这是一种减轻水污染和保护公众健康和环境的有趣方法。

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