• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于电催化硝酸盐/亚硝酸盐转化的能量供应和有价值产品合成的增值系统。

Valorization systems based on electrocatalytic nitrate/nitrite conversion for energy supply and valuable product synthesis.

作者信息

Feng Yi, Ren Jin-Tao, Sun Ming-Lei, Yuan Zhong-Yong

机构信息

School of Materials Science and Engineering, Smart Sensing Interdisciplinary Science Center, Nankai University Tianjin 300350 China

出版信息

Chem Sci. 2024 Nov 29;16(4):1528-1559. doi: 10.1039/d4sc05936k. eCollection 2025 Jan 22.

DOI:10.1039/d4sc05936k
PMID:39722785
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11668169/
Abstract

The excessive accumulation of nitrate/nitrite (NO ) in surface and groundwater has severely disrupted the global nitrogen cycle and jeopardized public health. The electrochemical conversion of NO to ammonia (NH) not only holds promise for ecofriendly NO removal, but also provides a green alternative to the energy-intensive Haber-Bosch process for NH production. Recently, in addition to the electrocatalyst design explosion in this field, many innovative valorization systems based on NO -to-NH conversion have been developed for generating energy and expanding the range of value-added products. Collective knowledge of advanced conversion systems is indispensable for restoring the global nitrogen cycle and promoting a N-based economy. Herein, a timely and comprehensive review is provided on the important progress of valorization systems based on NO conversion, including waste treatment systems, novel electrolytic systems, and energy conversion and storage systems. Some mechanism explorations, device designs, key electrode developments and feasibility analyses are involved to gain deeper understanding of various systems and facilitate implementing these cleaning systems in industry. Finally, challenges and future prospects are outlined in the NO conversion field with an aim to promote large-scale electrocatalytic system development and prosperous N-based electrochemistry.

摘要

硝酸盐/亚硝酸盐（NO ）在地表水和地下水中的过量积累严重扰乱了全球氮循环，并危及公众健康。将NO 电化学转化为氨（NH）不仅有望实现对NO 的生态友好型去除，还为生产NH的能源密集型哈伯-博施工艺提供了一种绿色替代方案。最近，除了该领域电催化剂设计的蓬勃发展外，许多基于NO 到NH转化的创新增值系统也已被开发出来，用于产生能量和扩大增值产品的范围。先进转化系统的综合知识对于恢复全球氮循环和推动氮基经济发展不可或缺。在此，本文对基于NO 转化的增值系统的重要进展进行了及时而全面的综述，包括废物处理系统、新型电解系统以及能量转换和存储系统。文中涉及了一些机理探索、装置设计、关键电极开发和可行性分析，以更深入地了解各种系统，并促进这些清洁系统在工业中的应用。最后，概述了NO 转化领域的挑战和未来前景，旨在推动大规模电催化系统的发展和繁荣氮基电化学。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/78b6a273119a/d4sc05936k-p4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/66eb13ea9513/d4sc05936k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/851d98e1e1df/d4sc05936k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/f3dcd944a692/d4sc05936k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/68faa21c6ac2/d4sc05936k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/73f10146fc54/d4sc05936k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/f607e52ae3bc/d4sc05936k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/f5c4e861135d/d4sc05936k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/9d55a1e58d0c/d4sc05936k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/5ff8eb8f929e/d4sc05936k-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/00f3d8b1d823/d4sc05936k-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/d7dfd06e79b2/d4sc05936k-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/a6bc084ce658/d4sc05936k-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/9e19d9613ac5/d4sc05936k-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/9b5899327a8f/d4sc05936k-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/7bdec1fe5d4c/d4sc05936k-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/3c3dfbb248cf/d4sc05936k-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/c5a1bc025dce/d4sc05936k-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/78b6a273119a/d4sc05936k-p4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/66eb13ea9513/d4sc05936k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/851d98e1e1df/d4sc05936k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/f3dcd944a692/d4sc05936k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/68faa21c6ac2/d4sc05936k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/73f10146fc54/d4sc05936k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/f607e52ae3bc/d4sc05936k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/f5c4e861135d/d4sc05936k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/9d55a1e58d0c/d4sc05936k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/5ff8eb8f929e/d4sc05936k-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/00f3d8b1d823/d4sc05936k-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/d7dfd06e79b2/d4sc05936k-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/a6bc084ce658/d4sc05936k-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/9e19d9613ac5/d4sc05936k-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/9b5899327a8f/d4sc05936k-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/7bdec1fe5d4c/d4sc05936k-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/3c3dfbb248cf/d4sc05936k-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/c5a1bc025dce/d4sc05936k-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c929/11752813/78b6a273119a/d4sc05936k-p4.jpg

相似文献

1
Valorization systems based on electrocatalytic nitrate/nitrite conversion for energy supply and valuable product synthesis.基于电催化硝酸盐/亚硝酸盐转化的能量供应和有价值产品合成的增值系统。
Chem Sci. 2024 Nov 29;16(4):1528-1559. doi: 10.1039/d4sc05936k. eCollection 2025 Jan 22.
2
Unveiling Cutting-Edge Developments in Electrocatalytic Nitrate-to-Ammonia Conversion.揭示电催化硝酸盐转化为氨的前沿进展。
Adv Mater. 2024 Apr;36(16):e2312746. doi: 10.1002/adma.202312746. Epub 2024 Jan 17.
3
Electrochemical Nitrate Reduction: Ammonia Synthesis and the Beyond.电化学硝酸盐还原：氨合成及其他
Adv Mater. 2024 Apr;36(17):e2304021. doi: 10.1002/adma.202304021. Epub 2023 Nov 2.
4
Microfluidics for Electrochemical Energy Conversion and Storage: Prospects Toward Sustainable Ammonia Production.用于电化学能量转换与存储的微流体技术：可持续氨生产的前景
Chem Rec. 2025 Apr;25(4):e202400234. doi: 10.1002/tcr.202400234. Epub 2025 Feb 5.
5
Electrochemical Selective Nitrate Reduction: Pathways to Nitrogen and Ammonia Production.电化学选择性硝酸盐还原：生成氮气和氨的途径。
Chem Rec. 2025 Feb;25(2):e202400206. doi: 10.1002/tcr.202400206. Epub 2024 Dec 23.
6
Copper single-atom catalyst as a high-performance electrocatalyst for nitrate-ammonium conversion.铜单原子催化剂作为用于硝酸盐-铵转化的高性能电催化剂。
J Hazard Mater. 2022 Jul 15;434:128892. doi: 10.1016/j.jhazmat.2022.128892. Epub 2022 Apr 19.
7
Advances in electrocatalytic nitrate reduction to ammonia over Cu-based catalysts.铜基催化剂上电化学催化硝酸盐还原制氨的研究进展
Environ Res. 2025 Jun 1;274:121123. doi: 10.1016/j.envres.2025.121123. Epub 2025 Feb 14.
8
Enzymatic Bioelectrosynthetic Ammonia Production: Recent Electrochemistry of Nitrogenase, Nitrate Reductase, and Nitrite Reductase.酶促生物电合成氨：固氮酶、硝酸还原酶和亚硝酸还原酶的近期电化学研究
Chempluschem. 2017 Apr;82(4):513-521. doi: 10.1002/cplu.201600442. Epub 2016 Oct 31.
9
NiP nanosheet array for high-efficiency electrohydrogenation of nitrite to ammonia at ambient conditions.用于在环境条件下高效电还原亚硝酸根为氨的 NiP 纳米片阵列。
J Colloid Interface Sci. 2022 Jan 15;606(Pt 2):1055-1063. doi: 10.1016/j.jcis.2021.08.050. Epub 2021 Aug 11.
10
Electrodegradation of nitrogenous pollutants in sewage: from reaction fundamentals to energy valorization applications.污水中含氮污染物的电极降解：从反应基本原理到能量回收应用
Chem Soc Rev. 2024 Dec 9;53(24):11908-11966. doi: 10.1039/d4cs00517a.

引用本文的文献

1
Hydrogen-bond mediated electrocatalytic nitrate reduction to ammonia over metal-organic frameworks with industrial current density.在具有工业电流密度的金属有机框架上，氢键介导的电催化硝酸盐还原制氨
Chem Sci. 2025 Jun 24. doi: 10.1039/d5sc02208h.

本文引用的文献

1
The Tandem Nitrate and CO Reduction for Urea Electrosynthesis: Role of Surface N-Intermediates in CO Capture and Activation.用于尿素电合成的串联硝酸盐和CO还原：表面N-中间体在CO捕获和活化中的作用
Angew Chem Int Ed Engl. 2024 Jun 10;63(24):e202403980. doi: 10.1002/anie.202403980. Epub 2024 May 3.
2
Efficient bubble/precipitate traffic enables stable seawater reduction electrocatalysis at industrial-level current densities.高效的气泡/沉淀物传输能够在工业级电流密度下实现稳定的海水还原电催化。
Nat Commun. 2024 Apr 5;15(1):2950. doi: 10.1038/s41467-024-47121-x.
3
RhNi Bimetallenes with Lattice-Compressed Rh Skin towards Ultrastable Acidic Nitrate Electroreduction.
具有晶格压缩Rh壳层的RhNi双金属烯用于超稳定酸性硝酸盐电还原
Adv Mater. 2024 Jun;36(23):e2314351. doi: 10.1002/adma.202314351. Epub 2024 Mar 4.
4
Ammonia Electrosynthesis from Nitrate Using a Ruthenium-Copper Cocatalyst System: A Full Concentration Range Study.使用钌-铜共催化剂体系从硝酸盐中电合成氨：全浓度范围研究
J Am Chem Soc. 2024 Jan 10;146(1):668-676. doi: 10.1021/jacs.3c10516. Epub 2023 Dec 28.
5
Electrochemical nitrate reduction in acid enables high-efficiency ammonia synthesis and high-voltage pollutes-based fuel cells.酸性条件下的电化学硝酸盐还原可实现高效氨合成及基于高电压污染物的燃料电池。
Nat Commun. 2023 Dec 5;14(1):8036. doi: 10.1038/s41467-023-43897-6.
6
Dynamically Adaptive Bubbling for Upgrading Oxygen Evolution Reaction Using Lamellar Fern-Like Alloy Aerogel Self-Standing Electrodes.使用层状蕨类合金气凝胶自支撑电极的动态自适应气泡法用于提升析氧反应
Adv Mater. 2024 Jan;36(1):e2307925. doi: 10.1002/adma.202307925. Epub 2023 Oct 12.
7
Integrated Tandem Electrochemical-chemical-electrochemical Coupling of Biomass and Nitrate to Sustainable Alanine.生物质与硝酸盐的集成串联电化学-化学-电化学耦合制备可持续丙氨酸
Angew Chem Int Ed Engl. 2023 Nov 6;62(45):e202311196. doi: 10.1002/anie.202311196. Epub 2023 Oct 2.
8
Efficient Hydrogen Evolution on Antiperovskite CuNCo Nanowires by Mo Incorporation and its Trifunctionality for Zn Air Batteries and Overall Water Splitting.通过掺入钼在反钙钛矿CuNCo纳米线上实现高效析氢及其在锌空气电池和全水解中的三重功能
Small. 2024 Jan;20(1):e2304541. doi: 10.1002/smll.202304541. Epub 2023 Sep 3.
9
Aqueous pulsed electrochemistry promotes C-N bond formation via a one-pot cascade approach.水相脉冲电化学通过一锅串联法促进C-N键的形成。
Nat Commun. 2023 Aug 22;14(1):5088. doi: 10.1038/s41467-023-40892-9.
10
Insights into the Diffusion Behaviors of Water over Hydrophilic/Hydrophobic Catalysts During the Conversion of Syngas to High-Quality Gasoline.合成气转化为高品质汽油过程中，水在亲水/疏水催化剂上扩散行为的见解
Angew Chem Int Ed Engl. 2023 Sep 11;62(37):e202306786. doi: 10.1002/anie.202306786. Epub 2023 Aug 3.