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树叶提取物介导合成氧化锌纳米结构用于增强赤藓红的光催化氧化

leaves extract-mediated synthesis of ZnO nanostructures for the enhanced photocatalytic oxidation of erythrosine.

作者信息

Parven Noshaba, Almani Khalida Faryal, Bhatti Muhammad Ali, Tahira Aneela, Shah Aqeel Ahmed, Nafady Ayman, Tonezzer Matteo, Ibupoto Zafar Hussain

机构信息

Departement of Pharmaceuticals, University of Sindh Jamshoro 76080 Pakistan.

Centre for Environmental Sciences, University of Sindh Jamshoro Sindh 76080 Pakistan.

出版信息

RSC Adv. 2025 Jan 27;15(4):2810-2824. doi: 10.1039/d4ra08782h. eCollection 2025 Jan 23.

Abstract

This study was focused on the development of ZnO nanostructures for the efficient oxidation of erythrosine dye and for studying the antibacterial activity of ZnO. It was observed that the phytochemicals from leaves modified the size, shape, crystalline properties and surface chemical composition of the ZnO nanostructures. ZnO nanostructures synthesized with 15 mL leaves extract (S-15) demonstrated highly efficient oxidation of erythrosine dye under the illumination of natural sunlight. Various photocatalyst evaluation parameters, such as initial dye concentration, pH of the dye solution, catalyst dose and cycling stability, were studied. The S-15 sample of ZnO exhibited almost 100% dye removal in an alkaline pH of 12 and a low concentration of 4.54 × 10 M. Furthermore, improved antibacterial activity was also observed against and bacteria strains. The use of leaves extract could be considered a low-cost, facile and ecofriendly green synthesis protocol for replacing the use of toxic chemicals and for eliminating the risk of releasing of toxic chemicals into the environment during the synthesis of high-performance nanostructured materials.

摘要

本研究聚焦于开发用于高效氧化赤藓红染料以及研究氧化锌抗菌活性的氧化锌纳米结构。据观察,来自树叶的植物化学物质改变了氧化锌纳米结构的尺寸、形状、晶体特性和表面化学成分。用15毫升树叶提取物合成的氧化锌纳米结构(S - 15)在自然阳光照射下对赤藓红染料表现出高效氧化作用。研究了各种光催化剂评估参数,如初始染料浓度、染料溶液的pH值、催化剂剂量和循环稳定性。氧化锌的S - 15样品在pH值为12的碱性条件下以及4.54×10⁻⁵M的低浓度下几乎实现了100%的染料去除。此外,还观察到对两种细菌菌株的抗菌活性有所提高。使用树叶提取物可被视为一种低成本、简便且环保的绿色合成方案,用于替代有毒化学品的使用,并消除在合成高性能纳米结构材料过程中向环境释放有毒化学品的风险。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c1b8/11771134/0296339d09e9/d4ra08782h-s1.jpg

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