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基于还原氧化石墨烯的杂化材料;V和Ru金属配合物的合成与表征

Hybrid Materials Based on Reduced Graphene Oxide; Synthesis and Characterization of V and Ru Metal Complexes.

作者信息

Bal Mustafa, Tontuş Mehmet İsa, Tümer Mehmet

机构信息

Department of Machinery and Metal Technologies, Airbus-TUSAŞ Aviation Vocational School, Istiklal University, Kahramanmaraş, Turkey.

Chemistry Department, K.Maras Sütcü Imam University, Kahramanmaraş, 46100, Turkey.

出版信息

J Fluoresc. 2025 Feb 12. doi: 10.1007/s10895-025-04184-3.

DOI:10.1007/s10895-025-04184-3
PMID:39939500
Abstract

The unique material graphene, which can find its place in many areas such as pharmaceutical industry, medical field, aviation and space industry, and elimination of environmental pollution; was obtained from graphite using strong oxidants within the scope of this study. rGO was obtained by thermal reduction of oxygen-containing groups in the GO material layer. Hybrid materials were synthesized by binding 4-aminobenzoic acid (C) and 3-aminobenzoic acid (D) to the rGO material. Ru metal complexes, which stand out with their superior photophysical properties, and V metal complexes, which are harmful to the environment and human health, were formed with the hybrid materials. The synthesized hybrid and complex materials were characterized by methods such as FTIR, UV-vis, XRD, SEM and EDX and TEM. In addition, the photoluminescence properties of the materials were analyzed. The potential of Ru and V complexes of the obtained hybrid materials for use in the environment and human health was evaluated.

摘要

独特的材料石墨烯可应用于制药行业、医学领域、航空航天工业以及消除环境污染等诸多领域;在本研究范围内,通过使用强氧化剂从石墨中获得了石墨烯。通过对氧化石墨烯(GO)材料层中的含氧基团进行热还原得到了还原氧化石墨烯(rGO)。通过将4-氨基苯甲酸(C)和3-氨基苯甲酸(D)与rGO材料结合,合成了杂化材料。与杂化材料形成了具有优异光物理性质的钌(Ru)金属配合物以及对环境和人类健康有害的钒(V)金属配合物。通过傅里叶变换红外光谱(FTIR)、紫外可见光谱(UV-vis)、X射线衍射(XRD)、扫描电子显微镜(SEM)和能谱分析(EDX)以及透射电子显微镜(TEM)等方法对合成的杂化材料和配合物进行了表征。此外,还分析了材料的光致发光性质。评估了所得杂化材料的钌和钒配合物在环境和人类健康方面的应用潜力。

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