Silicon/Hard Carbon Composites Synthesized from Phenolic Resin as Anode Materials for Lithium-Ion Batteries.

Silicon could revolutionize the performance of lithium-ion batteries (LIBs) due to its formidable theoretical gravimetric capacity, approximately ten times that of graphite. However, huge volume expansion during charge/discharge processes and poor electronic conductivity inhibited its commercialization. To address the problems, new carbon-silicon core-shell microparticles have emerged for prospective anodes in LIBs. In this study, we develop a core-shell structure by using hard carbon derived from phenolic resin as the core and nano silicon/pitch coating as the shell to the resulting HC@Si-P composite anode. A composition-optimized 20 wt.% pitch coated-Si/HC composite anode delivers superior cycling stability over 200 cycles under 1 A/g current density, showing a 398 mAh/g capacity. At 5.0 A/g current density during charge and discharge processes, the reversible capacity reaches 215 mAh/g. Upon reducing the current density to 0.1 A/g, the capacity remains high at 537 mAh/g. Impedance testing shows that after pitch coating, the RSEI impedance decreases and the diffusion coefficient of HC@Si-P increases. Moreover, the facile and scalable preparation technique is encouraging for the potential practical application of silicon-based anode materials of this type in the upcoming generation of LIBs.