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P 掺杂的 MoS/rGO 复合材料对析氢反应的增强电催化性能

Enhanced Electrocatalytic Performance of P-Doped MoS/rGO Composites for Hydrogen Evolution Reactions.

作者信息

Zhu Wenjun, Zhang Bofeng, Yang Yao, Zhao Minghai, Fang Yuwen, Cui Yang, Tian Jian

机构信息

School of Mechanical and Electrical Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, China.

Jingdezhen Mingxing Aerospace Forging Co., Ltd., Jingdezhen 333403, China.

出版信息

Molecules. 2025 Mar 7;30(6):1205. doi: 10.3390/molecules30061205.

Abstract

This study is based on the strategies of composite and element doping. Herein, P-MoS/rGO materials were synthesized using a solvent-assisted hydrothermal method. The MoS nanosheets were uniformly and vertically grown on rGO; meanwhile, the optimized structure of MoS was achieved by P doping, resulting in improved catalytic performance and structural stability. Under alkaline conditions, the P-MoS/rGO catalyst exhibits good electrocatalytic activity, demonstrating a Tafel slope of 70.7 mV dec and an overpotential of 172.8 mV at 10 mA/cm. Notably, even after 3000 consecutive LSV tests, the curves still show a high degree of overlap, indicating exceptional stability.

摘要

本研究基于复合和元素掺杂策略。在此,采用溶剂辅助水热法合成了P-MoS/rGO材料。MoS纳米片均匀且垂直地生长在rGO上;同时,通过P掺杂实现了MoS的优化结构,从而提高了催化性能和结构稳定性。在碱性条件下,P-MoS/rGO催化剂表现出良好的电催化活性,在10 mA/cm²时的塔菲尔斜率为70.7 mV/dec,过电位为172.8 mV。值得注意的是,即使经过3000次连续的线性扫描伏安(LSV)测试,曲线仍显示出高度重叠,表明具有优异的稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8cd3/11944752/ce5e64a346e2/molecules-30-01205-g001.jpg

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