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一种用于可食用电子产品集成的玉米基导电胶。

A Corn-Based Electrically Conductive Glue for Integration of Edible Electronics.

作者信息

Contreras-Pereda Noemí, Galli Valerio, Cataldi Pietro, Annese Valerio Francesco, Coco Giulia, Athanassiou Athanassia, Luzio Alessandro, Caironi Mario

机构信息

Center for Nano Science and Technology Istituto Italiano di Tecnologia Via R. Rubattino, 81 20134 Milan Italy.

Department of Physics Politecnico di Milano Piazza Leonardo da Vinci, 32 20133 Milan Italy.

出版信息

Small Sci. 2024 Dec 5;5(1):2400373. doi: 10.1002/smsc.202400373. eCollection 2025 Jan.

Abstract

Edible electronics leverages the electronic properties of food-grade materials to create non-toxic technologies that can be either environmentally degraded or digested by the body after the completion of their function. Various edible electronic components have been recently proposed, and their integration into more complex circuits and systems is urgently needed for point-of-care devices. In this context, developing a safe technology for interconnecting edible components is crucial. To this aim, here an edible electrically conductive adhesive made from zein, an edible protein derived from corn, and activated carbon, a food additive, are reported. Different formulations are proposed depending on the ratio between adhesive binder (zein) and electrically conductive filler (activated carbon), evidencing a trade-off between resistivity and adhesion, passing from a 3 × 10 Ω cm resistivity and 2 MPa lap shear adhesion strength to 5 × 10 Ω cm and 0.5 MPa values upon increasing the filler content. As a proof-of-concept, the conductive adhesive is validated in different applications relevant to edible electronics, such as mounting devices on top of innovative edible substrates, interconnecting state-of-the-art edible batteries, and conforming highly adhesive electrodes for fruit monitoring.

摘要

可食用电子产品利用食品级材料的电子特性来创造无毒技术,这些技术在完成其功能后可以被环境降解或被人体消化。最近已经提出了各种可食用电子元件,并且迫切需要将它们集成到更复杂的电路和系统中以用于即时检测设备。在这种背景下,开发一种用于连接可食用元件的安全技术至关重要。为此,本文报道了一种由玉米醇溶蛋白(一种从玉米中提取的可食用蛋白质)和活性炭(一种食品添加剂)制成的可食用导电粘合剂。根据粘合剂(玉米醇溶蛋白)和导电填料(活性炭)之间的比例提出了不同的配方,结果表明在电阻率和粘附力之间存在权衡,随着填料含量的增加,电阻率从3×10Ω·cm和搭接剪切粘附强度2MPa变为5×10Ω·cm和0.5MPa。作为概念验证,该导电粘合剂在与可食用电子产品相关的不同应用中得到了验证,例如将设备安装在创新的可食用基板上、连接最先进的可食用电池以及贴合用于水果监测的高粘性电极。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3722/11935078/eac54f7b028f/SMSC-5-2400373-g003.jpg

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