Gouda Abdelaziz, Merhi Nour, Hmadeh Mohamad, Cecchi Teresa, Santato Clara, Sain Mohini
Department of Applied Chemistry and Chemical Engineering University of Toronto 80 St. George Street Toronto ON M5S 3H6 Canada.
Centre for Biocomposites and Biomaterials Processing Division of Forestry Daniels Faculty of Architecture Landscape and Design University of Toronto Toronto ON M5S 3E8 Canada.
Glob Chall. 2025 Mar 7;9(4):2400240. doi: 10.1002/gch2.202400240. eCollection 2025 Apr.
The valorization of municipal solid waste permits to obtain sustainable functional materials. As the urban population burgeons, so does the volume of discarded waste, presenting both a challenge and an opportunity. Harnessing the materials and the latent energy within this solid waste not only addresses the issue of disposal but also contributes to the innovation of functional materials with applications in the energy, electronics, and environment sectors. In this perspective, technologies for converting, after sorting, municipal solid waste into valuable metals, chemicals, and fuels are critically analyzed. Innovative approaches to convert organic waste into functional carbon materials and to create, from plastic and electronic wastes, metal-organic frameworks for energy conversion, storage, and CO adsorption and conversion are proposed. Green hydrometallurgy routes that permit the recovery of precious metals avoiding noble metals' oxidative leaching, thus avoiding their downcycling, are also highlighted. The reclaimed precious metals hold promise for use in optoelectronic devices.
城市固体废物的增值利用有助于获得可持续的功能材料。随着城市人口的迅速增长,废弃垃圾的数量也在增加,这既带来了挑战,也带来了机遇。利用这些固体废物中的材料和潜在能量,不仅解决了处理问题,还推动了在能源、电子和环境领域具有应用价值的功能材料的创新。从这个角度出发,对将分类后的城市固体废物转化为有价值的金属、化学品和燃料的技术进行了批判性分析。提出了将有机废物转化为功能碳材料以及从塑料和电子废物中制备用于能量转换、存储以及二氧化碳吸附和转化的金属有机框架的创新方法。还强调了绿色湿法冶金路线,该路线能够回收贵金属,避免贵金属的氧化浸出,从而避免其降级循环利用。回收的贵金属有望用于光电器件。