Seddiq Mehdi, Alnajideen Mohammad, Navaratne Rukshan
College of Physical Sciences and Engineering, Cardiff University, Cardiff CF24 3AA, U.K.
City University of London, School of Science and Technology, 280 St John Street, London EC1 V 4PB, U.K.
Energy Fuels. 2025 Apr 15;39(16):7876-7889. doi: 10.1021/acs.energyfuels.4c04834. eCollection 2025 Apr 24.
Polymer electrolyte membrane fuel cells (PEMFCs) are gaining attention as viable energy carriers for future aerospace propulsion systems due to their high-power density, lightweight and compact design, zero emissions, scalability, quiet operation, and relatively reliable performance. However, maintaining optimal performance and durability under transient thermal conditions remains a critical challenge, particularly in aerospace environments. Despite extensive research on PEMFCs, the transient thermal effects remain underexplored. This study employs a validated numerical simulation model to investigate the transient responses of a PEMFC subjected to thermal shock cycles, where the bipolar plate walls experience abrupt temperature drops to 10 °C for durations of 3 to 19 s. The simulation model was benchmarked against experimental data from the literature, demonstrating deviations of less than 10% in the polarization curves, confirming its reliability for predicting transient behaviors. Results reveal that during these thermal shocks, the current density decreases by approximately 15%, from 9263 A/m at 50 °C to 7709 A/m at 10 °C, with recovery times exceeding 4 s. Significant deviations were observed in oxygen concentration, particularly at the cathode catalyst layer, where minimum levels decreased by over 20%. Similarly, the water content in the membrane showed an overshoot above steady-state levels postrecovery, remaining elevated for extended periods. Liquid water saturation in the gas diffusion layers (GDLs) increased significantly near the hydrogen inlets during cold conditions, obstructing reactant flow and further impacting performance. This study provides detailed predictions of the steady-state and transient responses of PEMFCs to temperature reduction cycles. The findings contribute to advancing thermal management strategies and improving system resilience under transient conditions, thereby addressing a key challenge in sustainable aviation.
聚合物电解质膜燃料电池(PEMFC)因其高功率密度、轻量化和紧凑设计、零排放、可扩展性、运行安静以及性能相对可靠等特点,正作为未来航空航天推进系统的可行能源载体而受到关注。然而,在瞬态热条件下维持最佳性能和耐久性仍然是一项关键挑战,尤其是在航空航天环境中。尽管对PEMFC进行了广泛研究,但瞬态热效应仍未得到充分探索。本研究采用经过验证的数值模拟模型,研究了PEMFC在热冲击循环下的瞬态响应,其中双极板壁温在3至19秒的持续时间内突然降至10°C。该模拟模型与文献中的实验数据进行了基准对比,结果表明极化曲线的偏差小于10%,证实了其预测瞬态行为的可靠性。结果显示,在这些热冲击期间,电流密度从50°C时的9263 A/m降至10°C时的7709 A/m,下降了约15%,恢复时间超过4秒。观察到氧浓度存在显著偏差,特别是在阴极催化剂层,其最低水平下降超过20%。同样,膜中的水含量在恢复后超过稳态水平出现过冲,并在较长时间内保持升高。在寒冷条件下,气体扩散层(GDL)中靠近氢气入口处的液态水饱和度显著增加,阻碍了反应物流动,进一步影响了性能。本研究提供了PEMFC对降温循环的稳态和瞬态响应的详细预测。这些发现有助于推进热管理策略,提高瞬态条件下的系统恢复能力,从而解决可持续航空中的一个关键挑战。