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聚苯乙烯/铜纳米复合箔:对……的光学增强和抗菌活性的双重功能

Nanocomposite Foils of PS/Cu : Dual Functionality of Optical Enhancement and Antibacterial Activity on .

作者信息

Barala Monika, Jaglan Jyoti, Mohan Devendra, Singh Namita, Sharma Chetan, Sanghi Sujata

机构信息

Department of Physics, Guru Jambheshwar University of Science and Technology, Hisar, 125001 India.

Department of Environmental Science and Engineering, Guru Jambheshwar University of Science and Technology, Hisar, 125001 India.

出版信息

Indian J Microbiol. 2025 Mar;65(1):389-404. doi: 10.1007/s12088-024-01388-2. Epub 2024 Sep 15.

Abstract

Copper nanoparticles embedded in polystyrene (PS) nanocomposite foils were prepared via the solution casting method to study their optical characteristics and antimicrobial activities. Structural and surface morphology of the prepared nanocomposite foils were carried out by FTIR and FESEM. UV-vis spectra reveal that the nanocomposite foils are optically transparent in the visible region, with a strong absorbance peak at ~ 264 nm. Optical parameters such as optical band gap (E), refractive index (n), extinction coefficient (k), and dielectric constants (ε, ε, tanδ) were calculated using UV-vis spectroscopy. The Single Oscillator Wemple DiDomenico model was employed to determine the dispersion energy characteristics (E, E), optical moments (M, M), and dispersion of refractive index (n). The nonlinear index of refraction (n) and third-order optical nonlinear susceptibility (χ) were calculated using Miller's expression. In-vitro antimicrobial activity was tested against Gram-negative bacterial species isolated from a hospital wastewater treatment plant, showing multiple drug resistance activity. The study revealed that PS/Cu nanocomposite foils exhibit promising results as optical limiters with significant antibacterial activity.

摘要

通过溶液浇铸法制备了嵌入聚苯乙烯(PS)纳米复合箔中的铜纳米颗粒,以研究其光学特性和抗菌活性。采用傅里叶变换红外光谱(FTIR)和场发射扫描电子显微镜(FESEM)对制备的纳米复合箔的结构和表面形态进行了表征。紫外可见光谱表明,纳米复合箔在可见光区域是光学透明的,在约264nm处有一个强吸收峰。利用紫外可见光谱计算了光学带隙(E)、折射率(n)、消光系数(k)和介电常数(ε、ε、tanδ)等光学参数。采用单振子Wemple DiDomenico模型确定了色散能量特性(E、E)、光学矩(M、M)和折射率色散(n)。利用米勒表达式计算了非线性折射率(n)和三阶光学非线性极化率(χ)。对从医院污水处理厂分离出的革兰氏阴性细菌进行了体外抗菌活性测试,结果显示其具有多重耐药活性。研究表明,PS/Cu纳米复合箔作为具有显著抗菌活性的光学限幅器表现出了良好的效果。

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