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通过亚波长椭球形介电纳米结构中的抗反射和米氏共振效应组合增强有机太阳能电池的吸收

Enhanced absorption in organic solar cells via combined anti-reflection and Mie resonance effects in subwavelength ellipsoidal dielectric nanostructures.

作者信息

Lim Donggyu, Ju Seongcheol, Kang Cheolhun, Kim Dohyun, Jung Jong Hoon, Kim Jeonghyun, Park Hui Joon, Lee Kyu-Tae

机构信息

Department of Physics, Inha University, Incheon, 22212, Republic of Korea.

Program in Semiconductor Convergence, Inha University, Incheon, 22212, Republic of Korea.

出版信息

Sci Rep. 2025 Jun 6;15(1):20028. doi: 10.1038/s41598-025-04980-8.

Abstract

This study presents subwavelength ellipsoidal dielectric nanostructures (SEDNs) to enhance absorption in organic solar cells (OSCs) through the combined effects of broadband anti-reflection (AR) and Mie scattering. Strong forward-directed scattering at shorter wavelengths is produced by the simultaneous excitation of both electric and magnetic moments in the SEDN, thereby lengthening the optical path length inside the active layer. Additionally, the SEDNs reduce reflection over a broad wavelength range, further enhancing absorption. By fine-tuning the structural parameters of the SEDN, including a minor axis diameter of 100 nm, a spacing of 30 nm, and an aspect ratio of 3.6 for TE polarization, a short-circuit current density (J) of 28.11 mA/cm is achieved, representing an 9.46% improvement over planar OSCs. Light scattering is analyzed through multipolar decomposition, while the AR effect is studied using optical admittance analysis. The proposed approaches not only offer performance enhancements for applications such as thin-film solar cells, photodetectors, nanoantennas, and metasurfaces, but also show potential for polarization-sensitive applications including bio-imaging, defect analysis, and optical security systems.

摘要

本研究提出了亚波长椭球形介电纳米结构(SEDNs),通过宽带抗反射(AR)和米氏散射的联合效应来增强有机太阳能电池(OSCs)中的吸收。SEDN中电矩和磁矩的同时激发在较短波长处产生强烈的前向散射,从而延长了有源层内的光程长度。此外,SEDNs在很宽的波长范围内降低反射,进一步增强吸收。通过微调SEDN的结构参数,包括短轴直径为100nm、间距为30nm以及TE偏振的纵横比为3.6,实现了28.11mA/cm的短路电流密度(J),比平面OSCs提高了9.46%。通过多极分解分析光散射,同时使用光学导纳分析研究AR效应。所提出的方法不仅为薄膜太阳能电池、光电探测器、纳米天线和超表面等应用提供性能提升,而且在包括生物成像、缺陷分析和光学安全系统在内的偏振敏感应用中也显示出潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b83/12144203/5a2963f4f564/41598_2025_4980_Fig1_HTML.jpg

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