用于可持续氢原子转移反应的基于十钨酸盐的离子液体光催化剂的设计与应用

Design and application of a decatungstate-based ionic liquid photocatalyst for sustainable hydrogen atom transfer reactions.

作者信息

Claros Miguel, Quévarec Julian, Fernández-García Sara, Noël Timothy

机构信息

Flow Chemistry Group, Van't Hoff Institute for Molecular Sciences (HIMS), Universiteit van Amsterdam (UvA) 1098 XH Amsterdam The Netherlands

Facultad de Química, Universidad de Murcia, Centro Multidisciplinar Pleiades-Vitalis Campus de Espinardo 30100 Murcia Spain.

出版信息

Green Chem. 2025 Jun 3;27(25):7660-7666. doi: 10.1039/d5gc02160j. eCollection 2025 Jun 23.

A recyclable decatungstate-based ionic liquid (DT-IL) was developed as a versatile photocatalyst for hydrogen atom transfer reactions. DT-IL exhibits broad solvent compatibility, high catalytic efficiency, and excellent recyclability. Its performance under batch and flow conditions, including in green and biphasic media, highlights its potential for sustainable photocatalysis.