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基于ZnO/MoS₂/WO₃/rGO的双频共振射频识别气体传感器在室内甲醛和氨气检测中的应用

Application of dual-frequency resonant RFID gas sensor based on ZnO/MoS₂/WO₃/rGO for indoor formaldehyde and ammonia detection.

作者信息

Miao Fengjuan, Wu Fan, Tao Bairui, Zhao Man

机构信息

College of Communications and Electronics Engineering, Qiqihar University, Qiqihar, 161006, Heilongjiang, China.

Suihua Univ, Suihua, 152061, Heilongjiang, People's Republic of China.

出版信息

Mikrochim Acta. 2025 Jun 12;192(7):418. doi: 10.1007/s00604-025-07285-9.

Abstract

A dual-frequency passive radio frequency identification (RFID) gas sensor based on zinc oxide (ZnO)/molybdenum disulfide (MoS)/tungsten trioxide (WO)/reduced graphene (rGO) is proposed for indoor detection of formaldehyde and ammonia concentrations. The antenna model is designed on the antenna simulation software, and then, the antenna is made by the engraving mechanism. Nano-sensitive materials are prepared by the hydrothermal method to characterize the materials, and then, different combinations of materials are coated on both sides of the antenna to produce gas-sensitive sensors. The experimental results show that one frequency point of the sensor works in the range of formaldehyde concentration of 0.08-1.14 ppm, amplitude variation is 17.11 dB, linearity R = 0.97. The sensor operates at another frequency in the ammonia concentration range of 5-100 ppm, the amplitude changes to 12.7 dB, and the linearity R = 0.99. Compared with the previous gas sensors, the sensor has wide measuring range, high sensitivity, good selectivity, is lightweight and portable, and provides high anti-interference ability.

摘要

提出了一种基于氧化锌(ZnO)/二硫化钼(MoS)/三氧化钨(WO)/还原氧化石墨烯(rGO)的双频无源射频识别(RFID)气体传感器,用于室内甲醛和氨浓度检测。在天线仿真软件上设计天线模型,然后通过雕刻机制制作天线。采用水热法制备纳米敏感材料并对其进行表征,然后将不同材料组合涂覆在天线两侧以制作气敏传感器。实验结果表明,该传感器的一个频率点在甲醛浓度为0.08 - 1.14 ppm范围内工作,幅度变化为17.11 dB,线性度R = 0.97。该传感器在氨浓度为5 - 100 ppm范围内的另一个频率下工作,幅度变化为12.7 dB,线性度R = 0.99。与以往的气体传感器相比,该传感器测量范围广、灵敏度高、选择性好、重量轻且便于携带,并具有高抗干扰能力。

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