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用于厨房应用中高效油水分离的碳化双层轻木膜

Carbonized Dual-Layer Balsa Wood Membrane for Efficient Oil-Water Separation in Kitchen Applications.

作者信息

Souare Mamadou, Dong Changqing, Hu Xiaoying, Zhang Junjiao, Xue Juejie, Zheng Quanjun

机构信息

National Engineering Laboratory for Biomass Power Generation Equipment, School of New Energy, North China Electric Power University, Beijing 102206, China.

State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206, China.

出版信息

Membranes (Basel). 2025 May 24;15(6):160. doi: 10.3390/membranes15060160.

Abstract

Wood-based membranes have garnered increasing attention due to their structural advantages and durability in the efficient treatment of oily kitchen wastewater. However, conventional fabrication methods often rely on toxic chemicals or synthetic processes, generating secondary pollutants and suffering from fouling, which reduces performance and increases resource loss. In this study, an innovative bilayer membrane was developed from balsa wood by combining a hydrophilic longitudinal layer for water transport with a polydimethylsiloxane (PDMS)-impregnated carbonized transverse layer to enhance hydrophobicity, resulting in increased separation efficiency and a reduction in fouling by 98.38%. The results show a high permeation flux of 1176.86 Lm h and a separation efficiency of 98.60%, maintaining low fouling resistance (<3%) over 20 cycles. Mechanical tests revealed a tensile strength of 10.92 MPa and a fracture elongation of 10.42%, ensuring robust mechanical properties. Wettability measurements indicate a 144° contact angle and a 7° sliding angle with water on the carbonized side, and a 163.7° contact angle with oil underwater and a 5° sliding angle on the hydrophilic side, demonstrating excellent selective wettability. This study demonstrates the potential of carbonized wood-based membranes as a sustainable, effective alternative for large-scale wastewater treatment.

摘要

木质基膜因其结构优势以及在高效处理含油厨房废水方面的耐久性而受到越来越多的关注。然而,传统的制造方法通常依赖有毒化学品或合成工艺,会产生二次污染物且存在污染问题,这会降低性能并增加资源损耗。在本研究中,通过将用于水传输的亲水性纵向层与浸渍聚二甲基硅氧烷(PDMS)的碳化横向层相结合,从轻木开发出一种创新的双层膜,以增强疏水性,从而提高分离效率并将污染减少98.38%。结果显示出1176.86 Lm h的高通量和98.60%的分离效率,在20个循环中保持低抗污染性(<3%)。力学测试显示拉伸强度为10.92 MPa,断裂伸长率为10.42%,确保了强大的力学性能。润湿性测量表明,碳化面与水的接触角为144°,滑动角为7°,亲水面在水下与油的接触角为163.7°,滑动角为5°,显示出优异的选择性润湿性。本研究证明了碳化木质基膜作为大规模废水处理的可持续、有效替代方案的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9356/12195240/13d47029e356/membranes-15-00160-g007.jpg

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