Santos Jorge, Silva Carlos, Fernandes Raquel A, Ferreira Nuno, Escobar-Avello Danilo, Magalhães Pedro, Magalhães Fernão D, Martins Jorge M, Carvalho Luisa H
ARCP-Associação Rede de Competência em Polímeros, 4200-355 Porto, Portugal.
LEPABE-Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s/n, 4200-465 Porto, Portugal.
Polymers (Basel). 2025 Jun 11;17(12):1619. doi: 10.3390/polym17121619.
The textile industry requires products with a wide range of characteristics for use in diverse applications such as the production of shoes, bags, jackets, thermal clothing and articles for the automotive industry, among others. These products have traditionally been made from leather, which is obtained from animal hides. However, leather production has come under enormous pressure due to sustainability concerns in various areas and the growing number of people who actively choose to avoid all animal products. The main solutions developed by the textile industry have been to apply synthetic coatings based on polyvinyl chloride (PVC) or polyurethane (PUR) to textile substrates. One of the ways to reduce the environmental impact and non-renewable content of artificial leather is to replace parts of the synthetic component with lignocellulosic by-products. In the present work the feasibility of using small branches and leaves of (BLE) as a component of an aqueous PUR formulation for coating textile products was evaluated. In addition, the possibility of obtaining functional textile products with antioxidant properties based on the BLE particles incorporation was also evaluated. The effect of the BLE particle size distribution in the PUR formulation and on the properties of the coated textile products was evaluated. The BLE particles and their size influenced the colour, appearance, hydrophobicity and mechanical properties of the coated textiles. The (BLE) particles have improved the tensile strength of textile coating products without loss of elongation, improving their properties for specific applications. Furthermore, the textiles coated with the (BLE) particles showed interesting antioxidant properties, being possible to obtain coated fabrics with five times more DPPH radical scavenging activity than the reference coated fabric without (BLE) particles.
纺织工业需要具有广泛特性的产品,用于多种应用,如鞋类、箱包、夹克、保暖服装以及汽车工业用品等的生产。这些产品传统上由皮革制成,皮革取自动物皮。然而,由于各领域对可持续性的关注以及越来越多的人积极选择避免使用所有动物产品,皮革生产面临巨大压力。纺织工业开发的主要解决方案是在纺织基材上涂覆基于聚氯乙烯(PVC)或聚氨酯(PUR)的合成涂层。减少人造革对环境的影响和不可再生成分的一种方法是用木质纤维素副产品替代部分合成成分。在本研究中,评估了使用 (BLE) 的小树枝和树叶作为水性 PUR 配方的成分用于涂覆纺织产品的可行性。此外,还评估了基于掺入 BLE 颗粒获得具有抗氧化性能的功能性纺织产品的可能性。评估了 PUR 配方中 BLE 粒径分布对涂覆纺织产品性能的影响。BLE 颗粒及其粒径影响了涂覆纺织品的颜色、外观、疏水性和机械性能。(BLE) 颗粒提高了纺织涂层产品的拉伸强度,而不损失伸长率,改善了其在特定应用中的性能。此外,涂覆有 (BLE) 颗粒的纺织品表现出有趣的抗氧化性能,有可能获得比不含 (BLE) 颗粒的参考涂覆织物具有五倍以上 DPPH 自由基清除活性的涂覆织物。