Hong Rongfu, Xing Lixin, Wu Mingjie, Chen Zhangsen, Wang Ning, Meng Ling, Ye Siyu, Wang Liguang, Zhang Gaixia, Du Lei
Huangpu Hydrogen Energy Innovation Centre/School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, P.R. China.
State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan 430200, P.R. China.
iScience. 2025 Jun 4;28(7):112820. doi: 10.1016/j.isci.2025.112820. eCollection 2025 Jul 18.
Renewable energy conversion and storage technologies, including batteries, fuel cells, and electrolyzers, have garnered global attention. Electrode materials are crucial in determining the performance and lifespan of the corresponding devices. Transition metals and light elements are key components in electrode materials, enabling efficient energy conversion by directly providing active sites or indirectly optimizing material electronic structures. To understand the relationship between electronic structures and device performance, advanced techniques like X-ray absorption spectroscopy (XAS) have been developed. Recently, resonant inelastic X-ray scattering (RIXS) features coupled with X-ray emission spectra (XES) have emerged as a complementary tool, providing additional insights into material electronic structures. This review focuses on recent advances in using XES, particularly RIXS, for studying energy conversion and storage materials, highlighting the unique features and potential of RIXS for electronic structure characterization and quantitative analysis. This work aims to stimulate interests in utilizing RIXS features in the field of energy conversion and storage.
包括电池、燃料电池和电解槽在内的可再生能源转换和存储技术已引起全球关注。电极材料对于确定相应器件的性能和寿命至关重要。过渡金属和轻元素是电极材料的关键组成部分,它们通过直接提供活性位点或间接优化材料电子结构来实现高效的能量转换。为了理解电子结构与器件性能之间的关系,人们开发了诸如X射线吸收光谱(XAS)等先进技术。最近,与X射线发射光谱(XES)相结合的共振非弹性X射线散射(RIXS)特性已成为一种补充工具,为材料电子结构提供了更多见解。本综述重点关注利用XES,特别是RIXS来研究能量转换和存储材料的最新进展,突出了RIXS在电子结构表征和定量分析方面的独特特性和潜力。这项工作旨在激发人们在能量转换和存储领域利用RIXS特性的兴趣。