• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

光催化中基于CsPbBr钙钛矿的异质结构：机理、稳定性及多功能性能

CsPbBr Perovskite-Based Heterostructures in Photocatalysis: Mechanisms, Stability, and Multifunctional Performance.

作者信息

Lv Kuanxin, Li Zhenzhen, Huang Xing, Cheng Zetong, Wang Zhongyan, Zhao Hang

机构信息

College of Metallurgy and Energy, North China University of Science and Technology, Tangshan, Hebei, 063210, China.

出版信息

Adv Sci (Weinh). 2025 Sep;12(34):e07747. doi: 10.1002/advs.202507747. Epub 2025 Jul 12.

DOI:10.1002/advs.202507747
PMID:40650696
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12442612/
Abstract

CsPbBr perovskite stands out as a promising photocatalyst due to its strong visible-light absorption and advantageous band positions, yet its practical application is constrained by rapid charge recombination and poor aqueous stability. This review systematically explores how heterostructure engineering, which encompasses Type-II, Z-scheme, and S-scheme architectures, overcomes these limitations by optimizing interfacial charge dynamics and enhancing material durability. The underlying mechanisms of band alignment, charge transfer pathways, and redox potential retention in heterostructures, alongside strategies for activity modulation and stability enhancement are analyzed. By integrating insights from structural design to functional performance, the review illuminates how CsPbBr-based heterostructures address critical challenges in photocatalysis, offering a comprehensive framework for advancing sustainable solutions in energy conversion and environmental remediation.

摘要

CsPbBr钙钛矿因其强烈的可见光吸收和有利的能带位置而成为一种有前途的光催化剂，然而其实际应用受到快速电荷复合和较差的水稳定性的限制。本综述系统地探讨了异质结构工程，包括II型、Z型和S型结构，如何通过优化界面电荷动力学和提高材料耐久性来克服这些限制。分析了异质结构中能带排列、电荷转移途径和氧化还原电位保持的潜在机制，以及活性调节和稳定性增强的策略。通过整合从结构设计到功能性能的见解，本综述阐明了基于CsPbBr的异质结构如何应对光催化中的关键挑战，为推进能源转换和环境修复的可持续解决方案提供了一个全面的框架。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/2298cac3414c/ADVS-12-e07747-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/219ba9327059/ADVS-12-e07747-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/bd1a550eca7a/ADVS-12-e07747-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/21b1fd6ca1bd/ADVS-12-e07747-g036.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/ae9182263778/ADVS-12-e07747-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/e9a6b703936b/ADVS-12-e07747-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/86284ee1595b/ADVS-12-e07747-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/0650ef465e5b/ADVS-12-e07747-g030.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/214d83711721/ADVS-12-e07747-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/896008ec74f3/ADVS-12-e07747-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/a9b107a2db41/ADVS-12-e07747-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/c380738faabd/ADVS-12-e07747-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/b52a587d334f/ADVS-12-e07747-g031.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/7fb8ffb14665/ADVS-12-e07747-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/dbf32cc0d879/ADVS-12-e07747-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/91ba78f2858c/ADVS-12-e07747-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/5ae406c50369/ADVS-12-e07747-g037.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/846517f4452e/ADVS-12-e07747-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/8e44d8029c86/ADVS-12-e07747-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/e25f5c996fe1/ADVS-12-e07747-g041.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/d946ac120d56/ADVS-12-e07747-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/941d09f518c4/ADVS-12-e07747-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/2298cac3414c/ADVS-12-e07747-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/219ba9327059/ADVS-12-e07747-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/bd1a550eca7a/ADVS-12-e07747-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/21b1fd6ca1bd/ADVS-12-e07747-g036.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/ae9182263778/ADVS-12-e07747-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/e9a6b703936b/ADVS-12-e07747-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/86284ee1595b/ADVS-12-e07747-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/0650ef465e5b/ADVS-12-e07747-g030.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/214d83711721/ADVS-12-e07747-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/896008ec74f3/ADVS-12-e07747-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/a9b107a2db41/ADVS-12-e07747-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/c380738faabd/ADVS-12-e07747-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/b52a587d334f/ADVS-12-e07747-g031.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/7fb8ffb14665/ADVS-12-e07747-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/dbf32cc0d879/ADVS-12-e07747-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/91ba78f2858c/ADVS-12-e07747-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/5ae406c50369/ADVS-12-e07747-g037.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/846517f4452e/ADVS-12-e07747-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/8e44d8029c86/ADVS-12-e07747-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/e25f5c996fe1/ADVS-12-e07747-g041.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/d946ac120d56/ADVS-12-e07747-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/941d09f518c4/ADVS-12-e07747-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d03e/12442612/2298cac3414c/ADVS-12-e07747-g023.jpg

相似文献

1
CsPbBr Perovskite-Based Heterostructures in Photocatalysis: Mechanisms, Stability, and Multifunctional Performance.光催化中基于CsPbBr钙钛矿的异质结构：机理、稳定性及多功能性能
Adv Sci (Weinh). 2025 Sep;12(34):e07747. doi: 10.1002/advs.202507747. Epub 2025 Jul 12.
2
Ultra-stable panchromatic luminescent BaMoO/CsPbX (X = Cl, Br, I) heterostructures by suppressing interfacial charge transfer.通过抑制界面电荷转移制备超稳定的全色发光 BaMoO/CsPbX（X = Cl、Br、I）异质结构
J Colloid Interface Sci. 2025 Aug 29;702(Pt 1):138883. doi: 10.1016/j.jcis.2025.138883.
3
Recent advances in g-CN-based S-scheme heterojunction photocatalysts: From design to application.基于g-CN的S型异质结光催化剂的最新进展：从设计到应用
Adv Colloid Interface Sci. 2025 Sep 4;346:103661. doi: 10.1016/j.cis.2025.103661.
4
Unraveling the Transformation from Type-II to Z-Scheme in Perovskite-Based Heterostructures for Enhanced Photocatalytic CO Reduction.揭示钙钛矿基异质结构中从II型到Z型的转变以增强光催化CO还原性能
J Am Chem Soc. 2024 Feb 7;146(5):3303-3314. doi: 10.1021/jacs.3c12073. Epub 2024 Jan 25.
5
Bismuth-based heterojunction photocatalysts for antibiotic remediation: A review of tetracycline degradation and mechanistic insights.用于抗生素修复的铋基异质结光催化剂：四环素降解综述及机理见解
J Environ Manage. 2025 Aug 29;393:127010. doi: 10.1016/j.jenvman.2025.127010.
6
Tailoring Multiscale Interfaces in Heterojunction Photocatalysis for NO Removal.用于去除 NO 的异质结光催化中多尺度界面的定制
ACS Appl Mater Interfaces. 2025 Jul 16;17(28):39809-39844. doi: 10.1021/acsami.5c06606. Epub 2025 Jul 2.
7
Long-Lived Charge Separation Enabled by Molecular Engineering of Phenazine-Based Hole Transport Materials.基于吩嗪的空穴传输材料的分子工程实现长寿命电荷分离
Small. 2025 Aug;21(31):e2501649. doi: 10.1002/smll.202501649. Epub 2025 Apr 18.
8
Interfacial S-scheme charge transfer in MgInS/ZnO heterojunction for enhanced photodegradation of tetracycline and efficient water splitting.用于增强四环素光降解和高效水分解的MgInS/ZnO异质结中的界面S型电荷转移
Nanoscale Adv. 2025 Jun 24. doi: 10.1039/d5na00573f.
9
Bromoacetyl Bromide-Derived CsPbBr Quantum Dots: Robust Water Stability for Aqueous-Phase Photocatalysis.溴乙酰溴衍生的CsPbBr量子点：用于水相光催化的强大水稳定性
Small. 2025 Aug;21(32):e2504049. doi: 10.1002/smll.202504049. Epub 2025 Jun 11.
10
Elbow Fractures Overview肘部骨折概述

本文引用的文献

1
Recent Advances in Innovative Device Designs and Engineering Strategies of Hybrid Perovskite Halides for Efficient Photoelectrochemical and Photocatalytic Applications.用于高效光电化学和光催化应用的混合钙钛矿卤化物创新器件设计与工程策略的最新进展
Small. 2025 Jul;21(26):e2501570. doi: 10.1002/smll.202501570. Epub 2025 May 8.
2
Interface Engineering, Charge Carrier Dynamics, and Solar-Driven Applications of Halide Perovskite/2D Material Heterostructured Photocatalysts.卤化物钙钛矿/二维材料异质结构光催化剂的界面工程、电荷载流子动力学及太阳能驱动应用
ACS Appl Mater Interfaces. 2025 Apr 23;17(16):23431-23465. doi: 10.1021/acsami.4c20972. Epub 2025 Apr 10.
3
CsPbBr-Modified Oxygen-Doped g-CN Heterojunctions for Sulfurization of Alkenes to Sulfoxides.
用于烯烃硫化制备亚砜的 CsPbBr 修饰的氧掺杂 g-CN 异质结
Inorg Chem. 2025 Apr 14;64(14):7009-7018. doi: 10.1021/acs.inorgchem.5c00287. Epub 2025 Apr 3.
4
Multisite Cross-Linked Ligand Suppressing Ion Migration for Efficient and Stable CsPbBr Perovskite Quantum Dot-Based Light-Emitting Diodes.用于高效稳定的基于CsPbBr钙钛矿量子点发光二极管的多位点交联配体抑制离子迁移
Angew Chem Int Ed Engl. 2025 May 12;64(20):e202422823. doi: 10.1002/anie.202422823. Epub 2025 Mar 6.
5
Perovskite Nanocrystal Self-Assemblies in 3D Hollow Templates.三维中空模板中的钙钛矿纳米晶自组装体
ACS Nano. 2025 Feb 25;19(7):6748-6757. doi: 10.1021/acsnano.4c07819. Epub 2025 Jan 13.
6
Bidentate Lewis Base Ligand-Mediated Surface Stabilization and Modulation of the Electronic Structure of CsPbBr Perovskite Nanocrystals.双齿路易斯碱配体介导的CsPbBr钙钛矿纳米晶体表面稳定化及电子结构调控
J Am Chem Soc. 2025 Jan 8;147(1):862-873. doi: 10.1021/jacs.4c13724. Epub 2024 Dec 20.
7
Unraveling the Ultrasonic-Assisted Synthesis of Green-Emitting CsPbBr@CsPbBr: Reaction Process, Luminescence Property, and Display Application.解析绿色发光的 CsPbBr@CsPbBr 的超声辅助合成：反应过程、发光特性及显示应用
Inorg Chem. 2024 Nov 4;63(44):20993-20999. doi: 10.1021/acs.inorgchem.4c02474. Epub 2024 Sep 25.
8
Mapping and Characterization of Local Structures of CsPbBr.CsPbBr₃局部结构的映射与表征
ACS Omega. 2024 Aug 9;9(33):35789-35797. doi: 10.1021/acsomega.4c04354. eCollection 2024 Aug 20.
9
Disentangling the effects of structure and lone-pair electrons in the lattice dynamics of halide perovskites.解析卤化物钙钛矿晶格动力学中结构和孤对电子的影响。
Nat Commun. 2024 May 17;15(1):4184. doi: 10.1038/s41467-024-48581-x.
10
A novel type-II-II heterojunction for photocatalytic degradation of LEV based on the built-in electric field: carrier transfer mechanism and DFT calculation.一种基于内建电场用于光催化降解左乙拉西坦的新型II-II型异质结：载流子转移机制及密度泛函理论计算
Sci Rep. 2024 May 9;14(1):10643. doi: 10.1038/s41598-024-60250-z.