Elshemy N S, Nassar S H, Elhawary Nancy S, Ali Mona M
Department of Dyeing and Textile Printing, Textile Institute, National Research Centre, Giza, Egypt.
Department of Dyeing, Printing, and Textile Auxiliaries, Textile Research and Technology Institute, National Research Centre, 33 El-Buhouth Street, Dokki, P.O. Box 12622, Cairo, Egypt.
Sci Rep. 2025 Jul 28;15(1):27377. doi: 10.1038/s41598-025-11544-3.
This study focuses on isolating a natural binder and thickening agent derived from the Aegle marmelous fruit. The isolated natural gum can be effectively employed as a binder and thickening agent in fabric printing applications. The findings indicate that this natural gum has remarkable rheological characteristics, essential for achieving optimal printing results. Microwave irradiation techniques and thermal bonding, varying in duration, power, and temperature, were employed to fix the printed samples that utilized the isolated natural gum. The results demonstrated that printed textiles exhibited excellent color fastness, with samples treated via microwave fixation showing enhanced color saturation, as evidenced by higher K/S values. A thorough evaluation of the physical and mechanical properties was conducted, including assessments of color yield, uniformity, absorption, and fixing efficiency. The results indicate that both weight loss and water absorption tend to increase over time. The natural gum isolated from Aegle marmelous shows minimal loss and absorption, in contrast to commercial gum (Sodium alginate), which exhibits significantly higher levels. Scanning electron microscopy (SEM) highlights distinct differences in particle morphology between the two types of gum; the commercial variety presents spherical aggregates, while the isolated natural gum features elongated thread-like particles. Extended microwave exposure leads to enhanced color intensity, which is influenced by the fabric structure and type of gum used. The K/S value peaks at 70 watts and subsequently decreases at 90 watts for printed cotton and cotton/polyester blends, while printed wool achieves the best results at 50 watts for 60 s. Closed samples consistently show enhanced K/S values, irrespective of the microwave settings. Regarding thermo fixation, as fixation temperatures and duration increase, K/S values typically rise, except for printed cotton. The K/S values reached their maximum at 160 °C for 6 min for wool and polyester/cotton blends, whereas cotton peaked at 140 °C under the same conditions. The observed variations in color yield, penetration, and fixation percentages among the different fabrics are attributed to their unique chemical compositions and characteristics, as well as the effects of microwave irradiation. Furthermore, employing pulsed microwave irradiation helps regulate temperature and mitigate exothermic reactions, resulting in improved dye-fabric interactions and overall stability of the dyeing process. This thorough analysis highlights the potential of utilizing natural agents derived from Aegle marmelous in contemporary textile printing, supporting sustainable practices while upholding performance standards.
本研究着重于从木苹果果实中分离出一种天然粘合剂和增稠剂。分离出的天然胶可有效地用作织物印花应用中的粘合剂和增稠剂。研究结果表明,这种天然胶具有显著的流变特性,这对于实现最佳印花效果至关重要。采用了持续时间、功率和温度各不相同的微波辐照技术和热粘合方法来固定使用分离出的天然胶的印花样品。结果表明,印花纺织品表现出优异的色牢度,经微波固定处理的样品颜色饱和度增强,较高的K/S值证明了这一点。对物理和机械性能进行了全面评估,包括对得色量、均匀性、吸色性和固色效率的评估。结果表明,失重和吸水性都倾向于随时间增加。与商业胶(海藻酸钠)相比,从木苹果中分离出的天然胶损失和吸收最小,而商业胶的损失和吸收则明显更高。扫描电子显微镜(SEM)突出了两种胶在颗粒形态上的明显差异;商业品种呈现球形聚集体,而分离出的天然胶具有细长的丝状颗粒。延长微波照射会导致颜色强度增强,这受织物结构和所用胶的类型影响。对于印花棉和棉/聚酯混纺织物,K/S值在70瓦时达到峰值,随后在90瓦时下降,而印花羊毛在50瓦照射60秒时效果最佳。封闭样品始终显示出更高的K/S值,与微波设置无关。关于热固色,随着固色温度和持续时间的增加,K/S值通常会升高,但印花棉除外。羊毛和聚酯/棉混纺织物在160°C下6分钟时K/S值达到最大值,而棉在相同条件下140°C时达到峰值。不同织物在得色量、渗透性和固色率方面观察到的差异归因于它们独特的化学成分和特性以及微波辐照的影响。此外,采用脉冲微波辐照有助于调节温度并减轻放热反应,从而改善染料与织物的相互作用以及染色过程的整体稳定性。这一全面分析突出了在当代纺织品印花中利用源自木苹果的天然剂的潜力,在坚持性能标准的同时支持可持续做法。