Alhussein Alaa N D, Qaid Mohammed R T M, Agliullin Timur, Valeev Bulat, Morozov Oleg, Sakhabutdinov Airat, Konstantinov Yuri A
Department of Radiophotonics and Microwave Technologies, Kazan National Research Technical University Named After A. N. Tupolev-KAI, 10, K. Marx St., Kazan 420111, Russia.
Perm Federal Research Center of the Ural Branch of the Russian Academy of Sciences (PFRC UB RAS), 13a Lenin St., Perm 614000, Russia.
Sensors (Basel). 2025 Jul 9;25(14):4275. doi: 10.3390/s25144275.
Measuring pH is a critical parameter in environmental monitoring, biomedical diagnostics, food safety, and industrial processes. Optical fiber sensors have proven highly effective for pH detection due to their exceptional sensitivity, rapid response, and resistance to electromagnetic interference, making them well suited for real-time monitoring. This review offers a comprehensive analysis of recent advances in optical fiber-based pH sensors, covering key techniques such as fluorescence-based, absorbance-based, evanescent wave, and interferometric methods. Innovations in Fiber Bragg Grating and Surface Plasmon Resonance technologies are also examined. The discussion extends to the impact of pH-sensitive coatings-ranging from nanomaterials and polymeric films to graphene-based compounds-on enhancing sensor performance. Recent advancements have also enabled automation in data analysis and improvements in remote sensing capabilities. The review further compares the economic viability of optical fiber sensors with traditional electrochemical methods, while acknowledging persistent issues such as temperature cross-sensitivity, long-term stability, and fabrication costs. Overall, recent developments have broadened the functionality and application scope of these sensors by improving efficiency, accuracy, and scalability. Future research directions are outlined, including advanced optical interrogation techniques, such as Addressed Fiber Bragg Structures (AFBSs), microwave photonic integration, and optimized material selection. These approaches aim to enhance performance, reduce costs, and enable the broader adoption of optical fiber pH sensors.
测量pH值是环境监测、生物医学诊断、食品安全和工业过程中的一个关键参数。光纤传感器因其卓越的灵敏度、快速响应和抗电磁干扰能力,已被证明在pH检测方面非常有效,使其非常适合实时监测。本文综述对基于光纤的pH传感器的最新进展进行了全面分析,涵盖了基于荧光、吸光度、倏逝波和干涉测量等关键技术。还研究了光纤布拉格光栅和表面等离子体共振技术的创新。讨论还涉及pH敏感涂层(从纳米材料、聚合物薄膜到基于石墨烯的化合物)对提高传感器性能的影响。最近的进展还实现了数据分析的自动化并改善了遥感能力。本文综述进一步比较了光纤传感器与传统电化学方法的经济可行性,同时承认存在诸如温度交叉敏感性、长期稳定性和制造成本等持续存在的问题。总体而言,最近的发展通过提高效率、准确性和可扩展性,拓宽了这些传感器的功能和应用范围。概述了未来的研究方向,包括先进的光学询问技术,如寻址光纤布拉格结构(AFBS)、微波光子集成和优化的材料选择。这些方法旨在提高性能、降低成本并使光纤pH传感器得到更广泛的应用。