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紫外线C光对室内空气化学的影响:一项建模研究。

The Impact of UVC Light on Indoor Air Chemistry: A Modeling Study.

作者信息

Carter Toby J, Shaw David R, Eadie Ewan, Jimenez Jose L, Olsiewski Paula J, Peng Zhe, Weschler Charles J, Carslaw Nicola

机构信息

Department of Environment and Geography, University of York, York YO10 5NG, U.K.

National Centre for Atmospheric Science, Department of Chemistry, University of York, York YO10 5DD, U.K.

出版信息

Environ Sci Technol. 2025 Aug 12;59(31):16543-16555. doi: 10.1021/acs.est.5c07414. Epub 2025 Jul 30.

Abstract

Germicidal ultraviolet light (GUV) is gaining attention for air disinfection, particularly following the COVID-19 pandemic. GUV air cleaning devices use 222 or 254 nm light to remove airborne and surface pathogens from indoor environments, although their impact on indoor chemistry has received limited attention. This modeling study investigates the impact of GUV light on indoor air pollutant concentrations. In a simulated, occupied classroom using a 222 nm lamp with an average room irradiance of 1 μW cm, the predicted ozone production rate was 0.33 mg h for an air change rate of 0.5 h, leading to surface interactions with occupants and inanimate surfaces that formed secondary products including nonanal, decanal, and 4-oxopentanal. By contrast, ozone concentration increased by 0.19 mg h at 0.5 h in the presence of a 254 nm lamp with an average room irradiance of 15 μW cm, primarily due to infiltration. The long-term health benefits of GUV light disinfection need to be quantitatively compared to the health harms due to GUV-induced pollution to allow a more complete assessment of the benefits of this technology.

摘要

杀菌紫外线(GUV)在空气消毒方面正受到越来越多的关注,尤其是在新冠疫情之后。GUV空气净化设备使用222纳米或254纳米的光来去除室内环境中的空气传播病原体和表面病原体,尽管其对室内化学的影响受到的关注有限。这项建模研究调查了GUV光对室内空气污染物浓度的影响。在一个模拟的、有人占用的教室里,使用一盏平均房间辐照度为1微瓦/平方厘米的222纳米灯,对于换气率为0.5次/小时的情况,预测的臭氧产生率为0.33毫克/小时,导致与居住者和无生命表面发生表面相互作用,形成包括壬醛、癸醛和4-氧代戊醛在内的二次产物。相比之下,在存在一盏平均房间辐照度为15微瓦/平方厘米的254纳米灯的情况下,0.5小时时臭氧浓度增加了0.19毫克/小时,主要是由于渗透作用。需要对GUV光消毒的长期健康益处与GUV诱导污染造成的健康危害进行定量比较,以便更全面地评估这项技术的益处。

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