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用(MN102)树脂对玉米纤维阿拉伯木聚糖提取物进行脱色:吸附性能和成膜能力

Decolorization of Corn Fiber Arabinoxylan Extract with (MN102) Resin: Adsorption Performance and Film-Forming Capacity.

作者信息

Weng Verónica, Gago Diana, Brazinha Carla, Alves Vítor D, Coelhoso Isabel M

机构信息

LAQV-REQUIMTE, Department of Chemistry, NOVA School of Science and Technology, NOVA University of Lisbon, 2829-516 Caparica, Portugal.

LEAF-Linking Landscape, Environment, Agriculture and Food, Instituto Superior de Agronomia, Universidade de Lisboa, Tapada da Ajuda, 1349-017 Lisbon, Portugal.

出版信息

Polymers (Basel). 2025 Aug 1;17(15):2128. doi: 10.3390/polym17152128.

Abstract

Arabinoxylan is a polysaccharide with film-forming properties, present in corn fiber, and a low-value by-product. The extract has a deep brown color, producing films of the same shade, which may not be appealing. This study addresses, for the first time, the adsorption of colored compounds present in an arabinoxylan extract using resin MN102. The resin successfully adsorbed the colored compounds from the arabinoxylan extract. After four consecutive adsorption/desorption cycles, the efficiency of the resin was similar, only decreasing from 63.3% to 52.9%. Langmuir and Freundlich models were fitted to the results of adsorption isotherm experiments, with the Freundlich model demonstrating the best fit to the experimental results. A fixed-bed column loaded with the resin was used for the removal of the colored compounds from the arabinoxylan extract, and the effect of the volumetric flow rate was investigated. The Yan and log-Gompertz models showed the best fit to the experimental breakthrough curves. This study systematically evaluated the adsorption conditions, providing a comprehensive analysis of the performance of the resin in the removal of the colored compounds. Additionally, the ability of the extract to maintain its film-forming properties after decolorization was evaluated, and some of the film's key characteristics were evaluated, namely its color, solubility in water and mechanical properties.

摘要

阿拉伯木聚糖是一种具有成膜特性的多糖,存在于玉米纤维中,是一种低价值的副产品。该提取物呈深褐色,制成的薄膜也是同样的颜色,可能不太吸引人。本研究首次探讨了使用MN102树脂对阿拉伯木聚糖提取物中存在的有色化合物进行吸附。该树脂成功吸附了阿拉伯木聚糖提取物中的有色化合物。经过四个连续的吸附/解吸循环后,树脂的效率相似,仅从63.3%降至52.9%。将朗缪尔模型和弗伦德里希模型拟合到吸附等温线实验结果中,结果表明弗伦德里希模型与实验结果拟合得最好。使用装有该树脂的固定床柱从阿拉伯木聚糖提取物中去除有色化合物,并研究了体积流速的影响。Yan模型和对数-冈珀茨模型与实验突破曲线拟合得最好。本研究系统地评估了吸附条件,全面分析了该树脂在去除有色化合物方面的性能。此外,还评估了提取物在脱色后保持其成膜特性的能力,并评估了薄膜的一些关键特性,即其颜色、在水中的溶解度和机械性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49a2/12349420/4b6cad0cb916/polymers-17-02128-g001.jpg

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