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壳聚糖基气凝胶吸附去除不同污染物的研究进展

Recent progress in adsorptive removal of different contaminants by chitosan-based aerogel.

作者信息

Shehab Mohammed Ahmed, Al-Lami Munaf, Taher Mohammad A, Mohammed Haidar Hasan, AbdulRazak Adnan A, Rashid Khalid T, Mahmood Alhafadhi, Abd Al-Ogaili Mohammed Faleh, Alsarayefi Saad

机构信息

Polymers and Petrochemicals Engineering Department, Basrah University for Oil and Gas Basrah 61004 Iraq

Department of Chemical Engineering and Petroleum Refining, Basrah University for Oil and Gas Basrah 61004 Iraq

出版信息

RSC Adv. 2025 Aug 22;15(36):29727-29742. doi: 10.1039/d5ra03536h. eCollection 2025 Aug 18.

Abstract

Rapid industrial development has led to the discharge of significant amounts of untreated industrial wastewater into the environment, resulting in substantial effects on natural ecosystems and human health. Consequently, there is a need to develop new environmentally friendly alternatives for water remediation. In this regard, chitosan (CS) aerogels possess high porosity, low density, and biodegradability, and act as effective sorbents for the removal of various ionic pollutants from water, air, and soil. The presence of numerous amino (-NH) and hydroxyl (OH) groups enhances the adsorption of ionic pollutants electrostatic interactions, hydrogen bonding, and chelation mechanisms. This review provides an overview of the use of chitosan-based aerogels as eco-friendly gels to remove different contaminants from water such as dyes, heavy metals, microorganisms, and pharmaceuticals, by improving the mechanical strength, decreasing hydrophilicity, and increasing acid stability. These improvements are accomplished using different modification methods, such as blending with nanofillers, chemical and/or ionic crosslinkers, and designing composite aerogels. The modified aerogel exhibits excellent adsorption ability against different contaminants, as well as antibacterial properties, making it promising candidates for a wide range of applications.

摘要

快速的工业发展导致大量未经处理的工业废水排放到环境中,对自然生态系统和人类健康产生了重大影响。因此,需要开发新的环境友好型水修复替代品。在这方面,壳聚糖(CS)气凝胶具有高孔隙率、低密度和生物可降解性,可作为有效的吸附剂,用于去除水、空气和土壤中的各种离子污染物。大量氨基(-NH)和羟基(OH)基团的存在通过静电相互作用、氢键和螯合机制增强了对离子污染物的吸附。本综述概述了基于壳聚糖的气凝胶作为环保凝胶的用途,通过提高机械强度、降低亲水性和增加酸稳定性,从水中去除不同的污染物,如染料、重金属、微生物和药物。这些改进是通过不同的改性方法实现的,如与纳米填料、化学和/或离子交联剂共混,以及设计复合气凝胶。改性气凝胶对不同污染物表现出优异的吸附能力以及抗菌性能,使其成为广泛应用的有前途的候选材料。

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